| 词条 | Lithium iodate |
| 释义 |
| verifiedrevid = 464390892 | ImageFile = LiIO3-skel.svg | ImageSize = 120px | ImageName = Skeletal formula of lithium iodate with I—O bond length | ImageFile1 = LiIO3-polyhedral.png | ImageSize1 = 160px | ImageName1 = Crystal structure of lithium iodate, iodines are inside the unit cell | IUPACName = Lithium iodate |Section1={{Chembox Identifiers | CASNo = 13765-03-2 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 3084149 | ChemSpiderID = 141432 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | EC_number = 237-365-2 | SMILES = [Li+].[O-]I(=O)=O | StdInChI = 1S/HIO3.Li/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = FZAXZVHFYFGNBX-UHFFFAOYSA-M | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | UNNumber = 1479 |Section2={{Chembox Properties | Formula = LiIO3 | Appearance = White hygroscopic crystals | Odor = Odorless | Density = 4.487 g/cm3[1] | MeltingPtC = 420-450 | MeltingPt_ref = [1][1][4] | Solubility = Anhydrous: 89.4 g/100 mL (10 °C) 82.7 g/100 mL (25 °C) 78.4 g/100 mL (40.1 °C) 73 g/100 mL (75.6 °C)[1] Hemihydrate: 80.2 g/100 mL (18 °C)[2] | SolubleOther = Insoluble in EtOH[1] | RefractIndex = 1.8875 (20 °C) 1.6 (RT) nHe–Ne: 1.8815 (20 °C)[1] 1.5928 (RT)[3] | ThermalConductivity = 1.27 W/m·K (a-axis) 0.65 W/m·K (c-axis)[1] | MagSus = −47.0·10−6 cm3/mol |Section3={{Chembox Structure | CrystalStruct = Hexagonal,[1] hP10[4] | SpaceGroup = P6322, No. 182[4] | PointGroup = 622[4] | LattConst_a = 5.46(9) Å | LattConst_c = 5.15(5) Å[4] | LattConst_gamma = 120 |Section7={{Chembox Hazards | GHSPictograms = {{GHS03}}{{GHS07}}{{GHS08}}[5] | GHSSignalWord = Danger | HPhrases = {{H-phrases|272|315|319|335|360}}[5] | PPhrases = {{P-phrases|201|220|261|305+351+338|308+313}}[5] | NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 2 | NFPA_ref = [6] }}Lithium iodate (LiIO3) is a negative uniaxial crystal[7] for nonlinear, acousto-optical and piezoelectric applications. It has been utilized for 347 nm ruby lasers.[8][9] PropertiesMohs hardness of lithium iodate is 3.5–4. Its linear thermal expansion coefficient at {{convert|298|K|C F}} is 2.8·10−5/°C (a-axis) and 4.8·10−5/°C (c-axis).[7] Its transition to β-form begin at {{convert|50|C|F}} and it is irreversible.[10]References1. ^1 2 {{CRC90}} {{Lithium compounds}}{{Inorganic-compound-stub}}2. ^{{cite book|last = Seidell|first = Atherton|last2 = Linke|first2 = William F.|year = 1919|title = Solubilities of Inorganic and Organic Compounds|publisher = D. Van Nostrand Company|place = New York City|edition = 2nd|page = 374}} 3. ^{{cite web|url = http://refractiveindex.info/?shelf=main&book=LiIO3&page=Herbst-o|title = Refractive index of LiIO3 (Lithium iodate) - Herbst-o|website = http://www.refractiveindex.info|first = Mikhail|last = Polyanskiy|accessdate = 2014-08-08}} 4. ^1 2 3 {{cite journal|title = Crystal Structure of Lithium Iodate|first1 = W.H.|last1 = Zachariasen|first2 = F.A. BartaLars|last2 = Olof|journal = Physical Review Letters|date = 1931-06-15|volume = 37|pages = 1626|doi = 10.1103/PhysRev.37.1626}} 5. ^1 2 {{Sigma-Aldrich|id=443964|name=Lithium iodate|accessdate=2014-08-08}} 6. ^{{cite web|url = https://www.pfaltzandbauer.com/MSDS/L04180%20%20SDS%20%2005202013.pdf|publisher = Pfaltz & Bauer, Inc.|place = Connecticut, USA|accessdate = 2014-08-08|website = https://www.pfaltzandbauer.com|title = SDS of Lithium iodate anhydrous}} 7. ^1 2 3 4 5 6 {{cite book|title = Rarely Used and Archive Crystals|journal = Nonlinear Optical Crystals: A Complete Survey|year = 2005|doi = 10.1007/0-387-27151-1_8|isbn = 978-0-387-27151-4|pages = 364–368|url = http://www.webcryst.com/zh/download/finish/6-/477-liio3-lithium-iodate.html}} 8. ^{{cite book|last1=Risk|first1=W. P.|last2=Gosnell|first2=T. R.|last3=Nurmikko|first3=A. V.|title=Compact Blue-Green Lasers|url=https://books.google.com/books?id=rtLwj5H9JacC&pg=PA123|accessdate=13 December 2012|date=9 January 2003|publisher=Cambridge University Press|isbn=978-0-521-52103-1|page=123}} 9. ^{{cite book|last=Nikogosyan|first=David N.|title=Nonlinear Optical Crystals: A Complete Survey|url=https://books.google.com/books?id=ZW9Ynx_Z7kkC&pg=PA371|accessdate=13 December 2012|date=4 January 2005|publisher=Springer|isbn=978-0-387-22022-2|page=371}} 10. ^1 {{cite journal|title = LiIO3 nanocrystals in SiO2 xerogels, a new material for non-linear optics|url = https://www.researchgate.net/profile/Yannick_Mugnier/publication/252139042_LiIO3_nanocrystals_in_SiO2_xerogels_a_new_material_for_nonlinear_optics/links/00b4952a1772abcc77000000|journal = Proceedings of SPIE|volume = 5222|issue = 26|date = 2003-11-20|first1 = Jeremie|last1 = Teyssier|first2 = Ronan Le|last2 = Dantec|first3 = Christine|last3 = Galez|first4 = Yannick|last4 = Mugnier|first5 = Jacques|last5 = Bouillot|first6= Jean-Claude|last6 = Plenet|doi = 10.1117/12.507309|citeseerx = 10.1.1.605.1743}} 3 : Lithium compounds|Iodates|Nonlinear optical materials |
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