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词条 Lithium polonide
释义

  1. Production

  2. Crystal structure

  3. References

{{Chembox
| PIN = Lithium polonide
|Section1 = {{Chembox Identifiers
|Section2 = {{Chembox Properties
| Formula = Li2Po
| MolarMass = 222.86 g/mol
| Appearance = greyish[1]
}}
}}Lithium polonide is a chemical compound with the formula Li2Po. It is a polonide, a set of very chemically stable compounds of polonium.[2][3]

Production

Lithium polonide may be produced from a redox reaction between aqueous hydrogen polonide and lithium metal[2][3] or from an acid-base reaction of H2Po with strong lithium-containing bases:

H2Po + 2 Li → Li2Po + H2

It may also be produced by heating lithium and polonium together at 300–400 °C.[1]

Crystal structure

Like sodium polonide, lithium polonide has the antifluorite structure.[2][3]

References

1. ^{{cite book |title=Advances in Inorganic Chemistry and Radiochemistry |chapter=The Chemistry of Polonium |last1=Bagnall |first1=K. W. |year=1962 |publisher=Academic Press |location=New York |isbn=9780120236046 |pages=197–230 |accessdate=June 17, 2012 |url=https://www.google.com/books?id=8qePsa3V8GQC}}
2. ^{{Greenwood&Earnshaw1st|page=899}}
3. ^{{citation | last = Moyer | first = Harvey V. | contribution = Chemical Properties of Polonium | pages = 33–96 | title = Polonium | url = http://www.osti.gov/bridge/servlets/purl/4367751-nEJIbm/ | editor-last = Moyer | editor-first = Harvey V. | id = TID-5221 | doi = 10.2172/4367751 | year = 1956 | location = Oak Ridge, Tenn. | publisher = United States Atomic Energy Commission}}.
{{Lithium compounds}}{{Polonium compounds}}{{inorganic-chemistry-stub}}

2 : Lithium compounds|Polonides

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