词条 | Littorine |
释义 |
| ImageFile = Littorine.svg | ImageSize = 200px | SystematicName = (1R,3r,5S)-8-Methyl-8-azabicyclo[3.2.1]octan-3-yl (R)-2-hydroxy-3-phenylpropanoate | OtherNames = |Section1={{Chembox Identifiers | CASNo = 21956-47-8 | PubChem = 443005 | ChemSpiderID = 391307 | SMILES = CN1[C@@H]2C[C@@H](OC([C@@H](CC3=CC=CC=C3)O)=O)C[C@H]1CC2 | InChI =1S/C17H23NO3/c1-18-13-7-8-14(18)11-15(10-13)21-17(20)16(19)9-12-5-3-2-4-6-12/h2-6,13-16,19H,7-11H2,1H3/t13-,14+,15+,16-/m1/s1 | InChIKey = FNRXUEYLFZLOEZ-FXUDXRNXSA-N |Section2={{Chembox Properties | C=17 | H=23 | N=1 | O=3 | Appearance = | Density = | MeltingPt = | BoilingPt = | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}Littorine is a tropane alkaloid found in a variety of plants including Datura[1] and Atropa belladonna.[2] It is closely related in chemical structure to atropine, hyoscyamine, and scopolamine, which all share a common biosynthetic pathway.[3][4] References1. ^{{Cite journal | last1 = Evans | first1 = W. C. | last2 = Ghani | first2 = A. | last3 = Woolley | first3 = V. A. | title = Distribution of littorine and other alkaloids in the roots of Datura species | journal = Phytochemistry | year = 1972 | volume = 11 | issue = 8 | pages = 2527–2529 | doi = 10.1016/S0031-9422(00)88530-1 }} 2. ^{{Cite journal | last1 = Nakanishi | first1 = F. | last2 = Sasaki | first2 = K. | last3 = Shimomura | first3 = K. | title = Isolation and identification of littorine from hairy roots of Atropa belladonna | journal = Plant Cell Reports | year = 1998 | volume = 18 | issue = 3–4 | pages = 249–251 | doi = 10.1007/s002990050565 }} 3. ^{{Cite journal | last1 = Zabetakis | first1 = I. | last2 = Edwards | first2 = R. | last3 = Hamilton | first3 = J. T. G. | last4 = O'Hagan | first4 = D. | title = The biosynthetic relationship between littorine and hyoscyamine in transformed roots of Datura stramonium | journal = Plant Cell Reports | year = 1998 | volume = 18 | issue = 3–4 | pages = 341–345 | doi = 10.1007/s002990050583 }} 4. ^{{Cite journal | last1 = Lanoue | first1 = A. | last2 = Boitel-Conti | first2 = M. | last3 = Portais | first3 = J.-C. | last4 = Laberche | first4 = J.-C. | last5 = Barbotin | first5 = J.-N. | last6 = Christen | first6 = P. | last7 = Sangwan-Norreel | first7 = B. | title = Kinetic Study of Littorine Rearrangement in Datura innoxia Hairy Roots by 13C NMR Spectroscopy | journal = Journal of Natural Products | year = 2002 | volume = 65 | issue = 8 | pages = 1131–1135 | pmid = 12193016 | doi = 10.1021/np010612c }} 3 : Tropane alkaloids|Tropane alkaloids found in Solanaceae|Carboxylate esters |
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