| 词条 | Loganic acid |
| 释义 |
| ImageFile = Loganic acid.svg | ImageSize = 150px | IUPACName = (1S,4aS,6S,7R,7aS)-1-(β-D-Glucopyranosyloxy)-6-hydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-4-carboxylic acid | OtherNames = |Section1={{Chembox Identifiers | CASNo = | PubChem = 89640 | ChemSpiderID = 80905 | SMILES = C[C@H]1[C@H](C[C@H]2[C@@H]1[C@@H](OC=C2C(=O)O)O[C@H]3[C@@H]([C@H]([C@@H]([C@H](O3)CO)O)O)O)O | InChI = 1/C16H24O10/c1-5-8(18)2-6-7(14(22)23)4-24-15(10(5)6)26-16-13(21)12(20)11(19)9(3-17)25-16/h4-6,8-13,15-21H,2-3H2,1H3,(H,22,23)/t5-,6+,8-,9+,10+,11+,12-,13+,15-,16-/m0/s1 | InChIKey = JNNGEAWILNVFFD-CDJYTOATBB | StdInChI = 1S/C16H24O10/c1-5-8(18)2-6-7(14(22)23)4-24-15(10(5)6)26-16-13(21)12(20)11(19)9(3-17)25-16/h4-6,8-13,15-21H,2-3H2,1H3,(H,22,23)/t5-,6+,8-,9+,10+,11+,12-,13+,15-,16-/m0/s1 | StdInChIKey = JNNGEAWILNVFFD-CDJYTOATSA-N |Section2={{Chembox Properties | C=16 | H=24 | O=10 | Appearance = | Density = | MeltingPt = | BoilingPt = | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}Loganic acid is an iridoid. Loganic acid is synthesized from 7-deoxyloganic acid by the enzyme 7-deoxyloganic acid hydroxylase (7-DLH).[1][2] It is a substrate for the enzyme loganate O-methyltransferase for the production of loganin.[3] References1. ^Salim, Yu, Altarejos and De Luca (2013) Virus-induced gene silencing identifies Catharanthus roseus 7-deoxyloganic acid-7-hydroxylase, a step in iridoid and monoterpene indole alkaloid biosynthesis. The Plant Journal. 76(5). 754-765 {{organic-compound-stub}}2. ^Miettinen, Dong, Navrot, Schneider, Burlat, et al. (2014) The seco-iridoid pathway from Catharanthus roseus. Nat Commun. 5( 3. ^Dewick (2009) Medicinal Natural Products: A Biosynthetic Approach. 4 : Iridoid glycosides|Glucosides|Carboxylic acids|Cyclopentanes |
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