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词条 Magnesium chromate
释义

  1. History

  2. Uses

  3. Hazards

  4. References

{{Chembox
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|Section1={{Chembox Identifiers
| CASNo = 13423-61-5
| PubChem = 61599
| ChemSpiderID = 55507
| SMILES = [O-][Cr](=O)(=O)[O-].[Mg+2]
| InChI = 1/Cr.Mg.4O/q;+2;;;2*-1/rCrO4.Mg/c2-1(3,4)5;/q-2;+2
| InChIKey = CRGGPIWCSGOBDN-OVNOGNLDAB
| StdInChI = 1S/Cr.Mg.4O/q;+2;;;2*-1
| StdInChIKey = CRGGPIWCSGOBDN-UHFFFAOYSA-N
|Section2={{Chembox Properties
|Mg=1
|Cr=1
|O=4
| Formula = MgCrO4
| MolarMass =
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|Section3={{Chembox Hazards
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Magnesium chromate is a chemical compound, with the formula MgCrO4. It is a white or brownish, odorless, water-soluble solid with several important industrial uses. This chromate can be manufactured as a powder.

History

Before 1940, the literature about Magnesium chromate and its hydrates was sparse, but studies starting in that year looked at its properties and solubility.[1]

Uses

It is available commercially in a variety of powders, from nanoscale to micron-sized, either as an anhydrous or hydrated form.[2][3]

As a hydrate, it is useful as a corrosion inhibitor and pigment,[4] or as an ingredient in cosmetics.[5]

In 2011, an undecahydrate (containing 11 molecules of water) of this compound was discovered by scientists at the University College London.[6]

Hazards

Magnesium chromate hydrate should be stored at room temperature, and there is no current therapeutic use.[7] It is a confirmed carcinogen, and can cause acute and dermititis, and possibly kidney and liver damage if inhaled, so it should be treated as a hazardous waste.[8]

References

1. ^{{cite journal|doi=10.1021/ja01865a059|year=1940|last1=Hill|first1=Arthur E.|title=The Systems Magnesium Chromate—Water and Ammonium Chromate—Water from 0 to 75°1|last2=Soth|first2=Glenn C.|last3=Ricci|first3=John E.|journal=Journal of the American Chemical Society|volume=62|issue=8|page=2131 }}
2. ^{{Cite web|url=http://www.americanelements.com/mgcrat.html|title=Magnesium Chromate|work=American Elements|accessdate=2013-07-16}}
3. ^{{cite journal|doi=10.4028/www.scientific.net/AMR.284-286.730|title=Synthesis of Nano-Crystalline Magnesium Chromate Spinel by Citrate Sol-Gel Method|year=2011|last1=Li|first1=Su Ping|last2=Jia|first2=Xiao Lin|last3=Qi|first3=Ya Fang|journal=Advanced Materials Research|volume=284-286|page=730}}
4. ^{{cite web|url=https://us.vwr.com/store/catalog/product.jsp?product_id=9880222 |title=Magnesium chromate hydrate, 99.8% (metals basis) |publisher=Us.vwr.com |date= |accessdate=2013-07-16}}
5. ^{{cite web|url=http://metal-powders-compounds.micronmetals.com/item/high-purity-metal-powders-compounds/magnesium-chromate/mg-401 |title=Item # MG-401, Heavy Magnesium Chromate Powder On Atlantic Equipment Engineers, A Division Of Micron Metals, Inc |publisher=Metal-powders-compounds.micronmetals.com |date= |accessdate=2013-07-16}}
6. ^{{cite journal|last1=Fortes|first1=A. Dominic |last2=Wood|first2=Ian G.|title=X-ray powder diffraction analysis of a new magnesium chromate hydrate, MgCrO4·11H2O|doi=10.1017/S088571561200005X|volume=27|issue=1|date=March 2012|pages=8–11|journal=Powder Diffraction}}
7. ^{{cite web|url=https://www.scbt.com/scbt/product/magnesium-chromate-hydrate-23371-94-0 |title=Magnesium chromate hydrate | CAS 23371-94-0 | Santa Cruz Biotech|publisher = Santa Cruz Biotechnology, Inc.|date= |accessdate=2013-07-16}}
8. ^{{Cite web|url=http://www.mcgean.com/documents/msds/usa-all/MS35500.pdf|title=Material Data Sheet|work=McGean-Rohco, Inc.|accessdate=2013-07-16}}
{{magnesium compounds}}

2 : Magnesium compounds|Chromates

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