| 词条 | Nitroapocynin |
| 释义 |
}}{{chembox | PIN = 1-(4-Hydroxy-3-methoxy-5-nitrophenyl)ethan-1-one | OtherNames = 1-(4-hydroxy-3-methoxy-5-nitrophenyl)ethanone 4'-Hydroxy-3'-methoxy-5'-nitroacetophenone Nitroapocynin 5-Nitroapocynin | ImageFile = 5-nitroapocynin.svg |Section1={{Chembox Identifiers | CASNo= 20716-41-0 | PubChem= 294764 | ChemSpiderID = 260051 | SMILES = CC(=O)C1=CC(=C(C(=C1)OC)O)[N+](=O)[O-] | StdInChI = 1S/C9H9NO5/c1-5(11)6-3-7(10(13)14)9(12)8(4-6)15-2/h3-4,12H,1-2H3 | StdInChIKey = PGKVPHVPNDBJTO-UHFFFAOYSA-N }} |Section2={{Chembox Properties | C=9 | H=9 | N=1 | O=5 | Appearance= Yellow powder | Density= | MeltingPtC= | BoilingPt= | Solubility= }} Nitroapocynin is a mono-nitrated form of apocynin. SynthesisApocynin can be nitrated with sodium nitrate and acidic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate in acetonitrile solvent.[1][2] References1. ^{{cite journal | doi = 10.1007/BF03246515| title = Using acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate in selective nitration of phenols under mild conditions| journal = Journal of the Iranian Chemical Society| volume = 6| pages = 159–164| year = 2009| last1 = Tajik| first1 = H.| last2 = Niknam| first2 = K.| last3 = Parsa| first3 = F.}} 2. ^{{cite journal | doi = 10.1107/S160053680903390X| title = 4-Hydroxy-3-methoxy-5-nitroacetophenone (5-nitroapocynin)| journal = Acta Crystallographica Section E| volume = 65| issue = 9| pages = o2292| year = 2009| last1 = Babu| first1 = Sainath| last2 = Raghavamenon| first2 = Achuthan C.| last3 = Fronczek| first3 = Frank R.| last4 = Uppu| first4 = Rao M.| pmid=21577684| pmc=2969931}} 4 : Nitrobenzenes|O-Methylated phenols|Vanilloids|Aromatic ketones |
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