On June 16, 1994, only 199 deputies voted for the appointment of Vitaliy Masol who headed the cabinet before and was ousted as result of intense student's protests known as the "Revolution on Granite". Masol's new government was Ukraine's third since Ukraine gained its independence in August 1991. Note that not all members of the Cabinet were ministers.
On April 4, 1995, the Cabinet was dismissed due to the vote of no confidence resolution adopted by the Supreme Council of Ukraine.
| Office | Name minister | Party |
|---|
| First Vice Prime Minister | Yukhym Zvyahilsky |
| Vice Prime Minister (on issues of Agro-Industrial Complex) | Volodymyr Demianov |
| Vice Prime Minister (on issues of Industry and Construction) | Vasyl Yevtukhov |
| Vice Prime Minister (on issues of Humanitarian Policy) | Mykola Zhulynsky |
| Vice Prime Minister (on issues of military–industrial complex) | Valeriy Shmarov |
| Vice Prime Minister (on issues of Foreign Economical Activity and Investments) | Valentyn Landyk |
| Chairman of State Property Fund | Volodymyr Pryadko |
| Chairman of Anti-Monopoly Committee | Oleksandr Zavada |
| Governor of National Bank of Ukraine | Viktor Yushchenko |
| Chairman of Security Service of Ukraine | Yevhen Marchuk |
| Chairman of State Committee of Border Guard | Valeriy Hubenko |
| Chairman of State Customs Committee | Anatoliy Kolos |
| Minister of Economy | Roman Shpek |
| Minister of Forest Business | Valeriy Samoplavsky |
| Minister of Machine-Building, Military-Industrial Complex and Conversion | Dmytro Chernenko |
| Minister of Rural Business and Provision | Yuriy Karasyk |
| Minister of Energy and Electrification | Vilen Semenyuk |
| Minister of Communication | Oleh Przhevalsky |
| Minister of Culture | Ivan Dzyuba |
| Minister on issues of Nationalities and Migration | Oleksandr Yemets |
| Minister of Education | Petro Talanchuk |
| Minister of Healthcare | Yuriy Spizhenko |
| Minister of Natural Environment | Yuriy Kostenko |
| Minister of Labor | Mykhailo Kaskevych |
| Minister of Industry | Anatoliy Holubchenko |
| Minister of Social Security of Population | Arkadiy Yershov |
| Minister of Statistics | Mykola Borysenko |
| Minister of Population Protection from consequences of Chornobyl Catastrophe | Heorhiy Hotovchyts |
| Minister of Youth and Sports | Valeriy Borzov |
| Minister of Cabinet of Ministers | Ivan Dotsenko |
| Minister of Construction and Architecture | Yuriy Serbin |
| Minister of Foreign Economic Relations | Oleh Slepichev |
| Minister of Defense | Vitaliy Radetsky |
| Minister of Finance | Hryhoriy Pyatachenko |
| Minister of Justice | Vasyl Onopenko |
| Minister of Internal Affairs | Andriy Vasylyshyn |
| Minister of Transport | Orest Klimpush |
| Minister of Foreign Affairs | Anatoliy Zlenko |
| Office | Name minister | Party |
|---|
| Prime Minister | Vitaliy Masol |
| First Vice Prime Minister | Valeriy Samoplavsky
Yevhen Marchuk |
| First Vice Prime Minister (on issues of Economic Reform) | Viktor Pynzenyk |
| First Vice Prime Minister - (on issues of Agro-Industrial Complex) | Petro Sabluk |
| Vice Prime Minister | Yevhen Marchuk |
| Vice Prime Minister | Anatoliy Dyuba |
| Vice Prime Minister | Volodymyr Plityn |
| Vice Prime Minister (on issues of Humanitarian Policy) | Ivan Kuras |
| Vice Prime Minister - Minister of Foreign Economical Relations | Serhiy Osyka |
| Vice Prime Minister - (on issues of Financing and Banking) | Ihor Mityukov |
| Vice Prime Minister - (on issues of Agro-Industrial Complex) | Petro Sabluk |
| Chairman of Security Service of Ukraine | Valeriy Malikov |
| Chairman of State Customs Committee | Yuriy Kravchenko |
| Chairman of State Committee of Border Guard | Viktor Bannykh |
| Minister of Healthcare | Volodymyr Maltsev
Volodymyr Bobrov |
| Minister on issues of Nationalities and Migration | Mykola Shulha |
| Minister of Machine-Building, Military-Industrial Complex and Conversion | Viktor Petrov |
| Minister of Finance | Petro Hermanchuk |
| Minister of Cabinet of Ministers | Valeriy Pustovoitenko |
| Minister of Internal Affairs | Volodymyr Radchenko |
| Minister of Foreign Affairs | Hennadiy Udovenko |
| Minister of Coal Industry | Viktor Poltavets |
| Minister of Press and Information | Mykhailo Onufriychuk |
| Minister of Education | Mykhailo Zghurovsky |
| Minister of Fishing Business | Mykola Shvedenko |
| Minister of Natural Environment and Nuclear Safety | Yuriy Kostenko |