“Tris(dimethylamino)gallium dimer”的意思、由来-开放百科全书

词条

Tris(dimethylamino)gallium dimer

释义

References

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| ImageFile = Tris(dimethylamino)gallium dimer.png
| ImageSize =
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| IUPACName =
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 180335-73-3
| PubChem =
| SMILES = CN(C)[Ga-]1(N(C)C)[N+](C)(C)[Ga-]([N+]1(C)C)(N(C)C)N(C)C}}
|Section2={{Chembox Properties
| C=12 | H=36 | Ga=2 | N=6
| MolarMass =
| Appearance =White or colorless solid
| Density =
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|Section3={{Chembox Hazards
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Tris(dimethylamino)gallium dimer, formally bis(μ-dimethylamino)tetrakis(dimethylamino)digallium, is an amide complex of gallium. This compound may be used as a precursor to other gallium complexes.

Commercially available, this compound may be prepared from lithium dimethylamide and gallium trichloride.^[1]

References

1. ^{{Cite journal | doi = 10.1016/S0277-5387(00)80578-1 | title = Structural and spectroscopic characterization of the compounds [Al(NMe2)3]2, [Ga(NMe2)3]2, [(Me2N)2Al{μ-N(H)1-Ad}]2 (1-Ad = 1-adamantanyl) and [{Me(μ-NPh2)Al}2NPh(μ-C6H4)] | year = 1990 | last1 = Waggoner | first1 = K.M. | last2 = Olmstead | first2 = M.M. | last3 = Power | first3 = P.P. | journal = Polyhedron | volume = 9 | issue = 2–3 | pages = 257–263}}

2 : Gallium compounds|Metal amides

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