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词条 Tungstic acid
释义

  1. Preparation

  2. Uses

  3. References

{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 428739474
| Name = Tungstic acid
| ImageFile1 = Acido tungstico.png
| ImageName1 = Tungstic acid
| ImageFile2 = Yellow Tungstic acid.jpg
| ImageName2 = Yellow tungstic acid
| IUPACName = dihydroxy-dioxotungsten
| OtherNames = Orthotungstic acid
|Section1={{Chembox Identifiers
| CASNo = 7783-03-1
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII = J4D6K0RX2G
| RTECS = YO7840000
| PubChem = 1152
| InChI = 1S/2H2O.2O.W/h2*1H2;;;/q;;;;+2/p-2
| InChIKey = CMPGARWFYBADJI-UHFFFAOYSA-L
| SMILES = O[W](=O)(=O)O
| EINECS = 231-975-2
|Section2={{Chembox Properties
| Formula = H2WO4
| MolarMass = 249.853 g/mol
| Appearance = yellow powder
| Density = 5.59 g/cm3
| Solubility = insoluble
| SolubleOther = soluble in HF, ammonia
slightly soluble in ethanol
| MeltingPtC = 100
| MeltingPt_notes = (decomposes)
| BoilingPtC = 1473
|Section3={{Chembox Structure
| Coordination =
| CrystalStruct =
|Section7={{Chembox Hazards
| ExternalSDS =
| EUClass =
| RPhrases =
| SPhrases =
| MainHazards =
| NFPA-H = 2
| NFPA-F = 0
| NFPA-R = 0
| NFPA-S =
| FlashPt =
|Section8={{Chembox Related
| OtherAnions =
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Tungstic acid refers to hydrated forms of tungsten trioxide, WO3. The simplest form, the monohydrate, is WO3·H2O, H2WO4. The dihydrate WO3·2H2O is also known. The solid-state structure of WO3·H2O consists of layers of octahedrally coordinated WO5(H2O) units where 4 vertices are shared.[1] The dihydrate has the same layer structure with the extra H2O molecule intercalated between the layers.[1] The monohydrate is a yellow solid and insoluble in water. The classical name for this acid is 'acid of wolfram'. Salts of tungstic acid are tungstates.

The acid was discovered by Carl Wilhelm Scheele in 1781.[2]

Preparation

Tungstic acid is obtained by the action of strong acids on solutions of alkali metallic tungstates. It may also be prepared from the reaction between hydrogen carbonate and sodium tungstate. It can also be obtained from pure tungsten by reaction with hydrogen peroxide.[3]

Uses

It is used as a mordant and a dye in textiles.

References

1. ^{{cite book|last=Wells|first=A.F.|title=Structural inorganic chemistry|year=1986|publisher=Clarendon Press|location=Oxford [Oxfordshire]|isbn=0-19-855370-6|edition=5th}}
2. ^Scheele, Carl Wilhelm (1781) [https://babel.hathitrust.org/cgi/pt?id=nyp.33433012786798;view=1up;seq=99 "Tungstens bestånds-delar"] (Tungsten's [i.e., Scheelite's] constituents), Kungliga Vetenskaps Academiens Nya Handlingar (Royal Scientific Academy's New Proceedings), 2: 89–95. (in Swedish)
3. ^{{cite news|last=Murau|first=P. C.|title=Dissolution of Tungsten by Hydrogen Peroxide|year=1961|publisher=Analytical Chemistry|DOI=10.1021/ac60176a021|pages=1125-1126}}
{{Tungsten compounds}}{{Authority control}}{{inorganic-compound-stub}}

3 : Tungstates|Tungstic acids|Transition metal oxoacids

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