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词条 1,2-Diiodoethylene
释义

  1. Preparation

  2. E-Z relative stability

  3. See also

  4. References

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477203654
| ImageFileL1 = Cis-isomer.png
| ImageSizeL1 =
| ImageNameL1 = Skeletal formula of cis-1,2-difluoroethene
| ImageFileL2 = Skeletal formula of Cis-1,2-DIIODOETHYLENE.png
| ImageNameL2 = Skeletal formula of Cis-1,2-DIIODOETHYLENE
| ImageSizeL2 =
| ImageFileR1 = Trans-isomer.png
| ImageNameR1 = Skeletal formula of trans-1,2-difluoroethene
| ImageSizeR1 =
| ImageFileR2 = Skeletal formula of Trans-1,2-DIIODOETHYLENE.png
| ImageNameR2 = Skeletal formula of Trans-1,2-DIIODOETHYLENE
| ImageSizeR2 =
| ImageCaptionL1= cis-1,2-Diiodoethene (Z)
| ImageCaptionR1= trans-1,2-Diiodoethene (E)
| ImageCaptionL2= cis-1,2-Diiodoethene (Z)
| ImageCaptionR2= trans-1,2-Diiodoethene (E)
| IUPACName = 1,2-Diiodoethylene
| OtherNames = 1,2-Diiodoethene
sym-Diiodoethylene
| Section1 = {{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 590-27-2
| CASNo_Comment = (Z)
| CASNo1 = 20244-70-6
| CASNo1_Comment = (E)
| EC_number = 209-821-0
| PubChem = 11537
| PubChem1 = 5463341
| PubChem1_Comment = (Z)
| PubChem2 = 5378102
| PubChem2_Comment = (E)
| ChemSpiderID = 4576037
| ChemSpiderID_Comment = (Z)
| ChemSpiderID1 = 4527007
| ChemSpiderID1_Comment = (E)
| InChI = 1S/C2H2I2/c3-1-2-4/h1-2H/b2-1+
| InChIKey = CVOGMKGEVNGRSK-OWOJBTEDSA-N
| SMILES = C(=CI)I
| SMILES2 = C(=C/I)\\I
}}
| Section2 = {{Chembox Properties
| C=2|H=2|I=2
| Appearance =
| MolarMass = 279.847 g/mol
| MeltingPtC = 73.4
| BoilingPtC = 196 to 197


}}
}}

1,2-Diiodoethylene, also known as 1,2-diiodoethene, is an organoiodide with the molecular formula C{{sub|2}}H{{sub|2}}I{{sub|2}}. It can exist as either of two geometric isomers, cis-1,2-diiodoethylene or trans-1,2-diiodoethylene.

Preparation

1,2-Diodoethylene can be made from acetylene bubbled into a solution of iodine and potassium iodide.[1]

E-Z relative stability

Like most cis-trans compounds, the Z isomer (cis) is less stable than the E isomer (trans) by 2 kcal/mol.{{citation needed|date=June 2017}}

See also

  • 1,1-Diiodoethane
  • 1,2-Diiodoethane

References

1. ^{{cite web|title=Synthesis of 1,2-diiodoethene|url=http://www.prepchem.com/synthesis-of-1-2-diiodoethene/|website=PrepChem.com|date=21 December 2015}}
{{DEFAULTSORT:Diiodoethylene, 1, 2-}}

3 : Organoiodides|Alkene derivatives|Halogenated solvents

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