| 词条 | Aminophosphonate |
| 释义 |
Phosphonates are more difficult to hydrolyse than phosphates.[3] PreparationAminophosphonates are often prepared by the condensation of imines and phosphorous acid (Pudovik reaction or Kabachnik–Fields reaction). More commonly the esters of phosphorous acid, e.g.diphenylphosphite, are employed. Because these compounds are of pharmaceutical interest, methods have been developed to induce these additions asymmetrically.[4] References1. ^{{cite journal|volume=350|year=2008|pages=1195–1208|title=Catalytic Enantioselective Hydrophosphonylation of Aldehydes and Imines|author=Pedro Merino|author2=Eugenia Marqués-López|author3=Raquel P. Herrera|journal=Advanced Synthesis & Catalysis|doi=10.1002/adsc.200800131}} 2. ^{{cite journal|last1=Tušek-Božić|first1=LJ|title=Aminophosphonate metal complexes of biomedical potential.|journal=Current Medicinal Chemistry|date=2013|volume=20|issue=16|pages=2096–117|pmid=23432587}} 3. ^{{cite journal|last1=Orsini|first1=F|last2=Sello|first2=G|last3=Sisti|first3=M|title=Aminophosphonic acids and derivatives. Synthesis and biological applications.|journal=Current Medicinal Chemistry|date=2010|volume=17|issue=3|pages=264–89|pmid=20214568}} 4. ^{{cite journal|volume=350|year=2008|pages=1195–1208|title=Catalytic Enantioselective Hydrophosphonylation of Aldehydes and Imines|author=Pedro Merino|author2=Eugenia Marqués-López|author3=Raquel P. Herrera|journal=Advanced Synthesis & Catalysis|doi=10.1002/adsc.200800131}} 2 : Amino acids|Phosphonic acids |
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