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词条 Arsonium
释义

  1. References

{{Chembox
| ImageFile1 = Arsonium-3D-vdW.png
| ImageSize1 =170px
| ImageAlt1 = Ball-and-stick model version of the arsonium ion
| SystematicName = Arsonium
| IUPACName =
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo = 53250-40-1
| PubChem = 5460506
| ChemSpiderID = 4574016
| SMILES = [AsH4+]
| InChI=1S/AsH4/h1H4/q+1
| InChIKey = VUEDNLCYHKSELL-UHFFFAOYSA-N
| RTECS =
| MeSHName =
| Gmelin = 322800
| ChEBI = CHEBI:30272 }}
|Section2={{Chembox Properties
| Formula = {{chem|As|H|4|+}}
| H=4 | As=1
| ConjugateBase = Arsine
| pKa =
}}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
|Section4={{Chembox Structure
| MolShape = Tetrahedral
}}
|Section6={{Chembox Related
| OtherCompounds = ammonium
phosphonium
}}
}}

The arsonium cation is a positively charged polyatomic ion with the chemical formula {{chem|AsH|4|+}}. An arsonium salt is a salt containing either the arsonium ({{chem|AsH|4|+}}) cation, such as arsonium bromide ({{chem|AsH|4|+|Br|-}}) and arsonium iodide ({{chem|AsH|4|+|I|-}}), which can be synthesized by reacting arsine with hydrogen bromide or hydrogen iodide.[1]. Or more commonly, as organic derivative such as the quaternary arsonium salts {{chem|Ph|4|As|+|Cl|-}} (CAS: [123334-18-9], hydrate form) and the zwitterionic compound arsenobetaine.

References

1. ^Muñoz‐Hernández, M. Á. (2006). Arsenic: Inorganic Chemistry. Encyclopedia of Inorganic Chemistry. pp 4. DOI: 10.1002/0470862106.ia013
{{chem-stub}}

2 : arsenic compounds|Cations

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