词条 | Arsonium |
释义 |
| ImageFile1 = Arsonium-3D-vdW.png | ImageSize1 =170px | ImageAlt1 = Ball-and-stick model version of the arsonium ion | SystematicName = Arsonium | IUPACName = | OtherNames = |Section1={{Chembox Identifiers | CASNo = 53250-40-1 | PubChem = 5460506 | ChemSpiderID = 4574016 | SMILES = [AsH4+] | InChI=1S/AsH4/h1H4/q+1 | InChIKey = VUEDNLCYHKSELL-UHFFFAOYSA-N | RTECS = | MeSHName = | Gmelin = 322800 | ChEBI = CHEBI:30272 }} |Section2={{Chembox Properties | Formula = {{chem|As|H|4|+}} | H=4 | As=1 | ConjugateBase = Arsine | pKa = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} |Section4={{Chembox Structure | MolShape = Tetrahedral }} |Section6={{Chembox Related | OtherCompounds = ammonium phosphonium }} }} The arsonium cation is a positively charged polyatomic ion with the chemical formula {{chem|AsH|4|+}}. An arsonium salt is a salt containing either the arsonium ({{chem|AsH|4|+}}) cation, such as arsonium bromide ({{chem|AsH|4|+|Br|-}}) and arsonium iodide ({{chem|AsH|4|+|I|-}}), which can be synthesized by reacting arsine with hydrogen bromide or hydrogen iodide.[1]. Or more commonly, as organic derivative such as the quaternary arsonium salts {{chem|Ph|4|As|+|Cl|-}} (CAS: [123334-18-9], hydrate form) and the zwitterionic compound arsenobetaine. References1. ^Muñoz‐Hernández, M. Á. (2006). Arsenic: Inorganic Chemistry. Encyclopedia of Inorganic Chemistry. pp 4. DOI: 10.1002/0470862106.ia013 {{chem-stub}} 2 : arsenic compounds|Cations |
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