| 词条 | Bathocuproine |
| 释义 |
| ImageFile = Cuproine.png | ImageSize = | ImageAlt = | IUPACName = | OtherNames = 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, 2,9-Dimethyl-4,7-diaphenyl-1,10-phenanthroline 2,9-Dimethyl-4,7-diphenylphenanthroline, 4,7-Diphenyl-2,9-dimethyl-1,10-phenanthroline, BCP |Section1={{Chembox Identifiers | CASNo = 4733-39-5 | PubChem = 65149 | EC_number = 225-240-5 | UNII = 9THP2V94FX | ChEMBL = 220061 | ChemSpiderID = 58658 | StdInChI=1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3 | StdInChIKey = STTGYIUESPWXOW-UHFFFAOYSA-N | SMILES = CC1=NC2=C(C=CC3=C2N=C(C=C3C4=CC=CC=C4)C)C(=C1)C5=CC=CC=C5 |Section2={{Chembox Properties | C=26|H=20|N=2 | MolarMass = | Appearance = Pale yellow solid | Density = | MeltingPtC = 283 | BoilingPt = | Solubility = organic solvents}} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = | GHSPictograms = {{GHS07}} | GHSSignalWord = Warning | HPhrases = {{H-phrases|302|413}} | PPhrases = {{P-phrases|264|270|273|301+312|330|501}} }} }}Bathocuproine is a derivative of 1,10-phenanthroline with two methyl groups and two phenyl groups in the 4,7 and 2,9 positions, respectively. Like 1,10-phenanthroline, bathocuproine is a bidentate chelating ligand. The two methyl groups flank the nitrogen centers, such that bathocuproine is a bulky ligand. It is a pale yellow solid that is soluble in polar organic solvents.[1] References1. ^{{cite encyclopedia|author=Guosheng Liu, Yichen, Wu|year=2012|title = Encyclopedia of Reagents for Organic Synthesis|doi=10.1002/047084289X.rn01392|encyclopedia=eEROS|chapter=Bathocuproine|isbn=0471936235}} 2 : Chelating agents|Phenanthrolines |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。