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词条 Belakovskiite
释义

  1. Association

  2. Crystal structure

  3. References

{{infobox mineral
| name = Belakovskiite
| category = Sulfate mineral
| image =
| imagesize =
| alt =
| caption =
| formula = Na7(UO2)(SO4)4(SO3OH)(H2O)3
| strunz =
| dana =
| system = Triclinic
| class = Pinacoidal ({{overline|1}})
(same H-M symbol)
| symmetry = P{{overline|1}}
| unit cell = a = 5.46, b = 11.33,
c = 18.42 [Å], α = 104.77°,
β = 90.09°, γ = 96.77° (approximated); Z = 2
| color = Yellow-green
| colour =
| habit = fibrous
| twinning =
| cleavage = None
| fracture =
| tenacity = Brittle
| mohs = 2
| luster = Vitreous
| streak = White
| diaphaneity = Transparent
| gravity =
| density = 3.31 (calculated); 3.23 (measured)
| polish =
| opticalprop = Biaxal (+)
| refractive = nα=1.50, nβ=1.51, nγ=1.52 (approximated)
| birefringence =
| pleochroism = None
| 2V = 88o (calculated)
| dispersion =
| extinction =
| length fast/slow =
| fluorescence =
| absorption =
| melt =
| fusibility =
| diagnostic =
| solubility =
| impurities =
| alteration =
| other = Radioactive
| references = [1][2][1]
}}Belakovskiite is a very rare uranium mineral with the formula Na7(UO2)(SO4)4(SO3OH)(H2O)3.[2][3] It is interesting in being a natural uranyl salt with hydrosulfate anion, a feature shared with meisserite.[4] Other chemically related minerals include fermiite, oppenheimerite, natrozippeite and plášilite.[5][6][7][8] Most of these uranyl sulfate minerals was originally found in the Blue Lizard mine, San Juan County, Utah, US.[9] The mineral is named after Russian mineralogist Dmitry Ilych Belakovskiy.[2]

Association

Belakovskiite is associated with other sulfate minerals: meisserite, blödite, ferrinatrite, kröhnkite, and metavoltine.[2]This association is found as efflorescences on a sandstone associated with uranium mineralization.[1]

Crystal structure

The framework of belakovskiite is unique. The main building block of its crystal structure is a hexavalent cluster with composition (UO2)(SO4)4(H2O). Such clusters are connected via Na-O and hydrogen bonds.[2]

References

1. ^{{cite web|url=http://www.handbookofmineralogy.org/pdfs/belakovskiite.pdf |title=Belakovskiite - Handbook of Mineralogy |website=Handbookofmineralogy.org |accessdate=2016-03-10}}
2. ^Kampf, A.R., Plášil, J., Kasatkin, A.V., and Marty, J., 2014. Belakovskiite, Na7(UO2)(SO4)4(SO3OH)(H2O)3, a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine 78(3), 639-649
3. ^{{cite web |url=http://www.mindat.org/min-45960.html |title=Belakovskiite: Belakovskiite mineral information and data |website=Mindat.org |accessdate=2016-03-10}}
4. ^{{cite web |url=http://www.mindat.org/min-43905.html |title=Meisserite: Meisserite mineral information and data |website=Mindat.org |accessdate=2016-03-10}}
5. ^{{cite web|url=http://www.mindat.org/min-46506.html |title=Fermiite: Fermiite mineral information and data |website=Mindat.org |accessdate=2016-03-10}}
6. ^{{cite web|url=http://www.mindat.org/min-46514.html |title=Oppenheimerite: Oppenheimerite mineral information and data |website=Mindat.org |accessdate=2016-03-10}}
7. ^{{cite web|url=http://www.mindat.org/min-3694.html |title=Natrozippeite: Natrozippeite mineral information and data |website=Mindat.org |accessdate=2016-03-10}}
8. ^{{cite web|url=http://www.mindat.org/min-46145.html |title=Plášilite: Plášilite mineral information and data |website=Mindat.org |accessdate=2016-03-10}}
9. ^{{cite web|url=http://www.mindat.org/loc-38665.html |title=Blue Lizard Mine, Chocolate Drop, Red Canyon, White Canyon District, San Juan Co., Utah, USA - Mindat.org |website=Mindat.org |accessdate=2016-03-10}}
{{sulfate-mineral-stub}}

4 : Uranium minerals|Sulfate minerals|Sodium minerals|Triclinic minerals

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