| 词条 | Bis(trimethylsilyl) peroxide |
| 释义 |
| ImageFile = Tms2O2.png | ImageSize = | ImageAlt = | IUPACName = | OtherNames = |Section1={{Chembox Identifiers | CASNo = 5796-98-5 | PubChem = 10058088 | InChI=1S/C6H18O2Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3 | InChIKey = XPEMYYBBHOILIJ-UHFFFAOYSA-N | SMILES = C[Si](C)(C)OO[Si](C)(C)C }} |Section2={{Chembox Properties | C=6|H=18|Si=2|O=2 | MolarMass = | Appearance = colorless oil | Density = | MeltingPt = | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }}Bis(trimethylsilyl) peroxide is an organosilicon compound with the formula ((CH3)3SiO)2. It is a colorless liquid that is soluble in organic solvents so long as they lack acidic groups. The compound represents an aprotic analogue of hydrogen peroxide and as such it is used for certain sensitive organic oxidations. Upon treatment with organolithium compounds, it affords the silyl ether. It is prepared by treating trimethylsilyl chloride with anhydrous adducts of hydrogen peroxide, e.g. Hydrogen peroxide-urea complex.[1] References1. ^{{cite encyclopedia|title=Bis(trimethylsilyl) Peroxide|authors=Jih Ru Hwu, Buh-Luen Chen, Santhosh F. Neelamkavil, Yuzhong Chen|year=2002|doi=10.1002/047084289X.rb219.pub3|encyclopedia=e-EROS Encyclopedia of Reagents for Organic Synthesis}} 4 : Trimethylsilyl compounds|Organic peroxides|Reagents for organic chemistry|Oxidizing agents |
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