“Bromochlorobenzene”的意思、由来-开放百科全书

Bromochlorobenzene is any of three different positional isomers consisting of a bromine atom and a chlorine atom as substituents on a benzene ring.

Isomers of Bromochlorobenzene

Skeletal formula

General

Common names

o-bromochlorobenzene
ortho-bromochlorobenzene

m-bromochlorobenzene
meta-bromochlorobenzene

p-bromochlorobenzene
para-bromochlorobenzene

Systematic name

1-bromo-2-chlorobenzene

1-bromo-3-chlorobenzene

1-bromo-4-chlorobenzene

Molecular formula

BrC₆H₄Cl

Molar mass

191.45 g/mol

CAS number

localValue=694-80-4}}

localValue=108-37-2}}

localValue=106-39-8}}

ChemSpider

localValue=12230}}

localValue=13875377}}

localValue=7518}}

CID|Compound ID}}

localValue=12754}}

localValue=7928}}

localValue=7806}}

Properties

Melting point

-13|°C|K}}

-22|°C|K}}

63-67|°C|K}}

Boiling point

203-205|°C|K}}

195-196|°C|K}}

196|°C|K}}

References

1. ^{{OrgSynth |first= Jonathan L. |last= Hartwell |year=1944 |title= o-Chlorobromobenzene |volume= 24 |pages= 22 |prep= CV3P0185 }}
2. ^{{cite journal |doi=10.1021/jo00380a031|title=Use of aryltrimethylgermanium substrates for facile aromatic chlorination, bromination, and iodination|journal=The Journal of Organic Chemistry|volume=52|issue=4|pages=664–667|year=1987|last1=Moerlein|first1=S. M.}}
3. ^{{cite journal |doi=10.1246/cl.1981.243|title=Carbon–silicon bond cleavage of organotrialkoxysilanes and organosilatranes with m-chloroperbenzoic acid and N-bromosuccinimide. New route to phenols, primary alcohols and bromides|journal=Chemistry Letters|volume=10|issue=2|pages=243–246|year=1981|last1=Hosomi|first1=Akira|last2=Iijima|first2=Susumu|last3=Sakurai|first3=Hideki}}
4. ^{{cite journal|doi=10.1021/ja01059a073|title = Studies in Organophosphorus Chemistry. I. Conversion of Alcohols and Phenols to Halides by Tertiary Phosphine Dihalides|journal = Journal of the American Chemical Society|volume = 86|issue = 5|pages = 964–965|year = 1964|last1 = Wiley|first1 = G. A.|last2 = Hershkowitz|first2 = R. L.|last3 = Rein|first3 = B. M.|last4 = Chung|first4 = B. C.}}
5. ^{{cite journal |doi=10.1021/jo00297a087|title=Preparation of aryl chlorides from phenols|journal=The Journal of Organic Chemistry|volume=55|issue=10|pages=3415–3417|year=1990|last1=Bay|first1=Elliott|last2=Bak|first2=David A.|last3=Timony|first3=Peter E.|last4=Leone-Bay|first4=Andrea}}

2 : Chloroarenes|Bromoarenes