| 词条 | (Butadiene)iron tricarbonyl |
| 释义 |
| ImageFile = Butadiene iron tricarbonyl.png | ImageSize = 144 | ImageAlt = | IUPACName = | OtherNames = |Section1={{Chembox Identifiers | CASNo = 12078-32-9 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 11965858 | PubChem1 = 25509 | EINECS = 235-140-3 | StdInChI=1S/C4H6.3CO.Fe/c1-3-4-2;3*1-2;/h3-4H,1-2H2;;;; | InChIKey = NBFCJULAAWWTBL-UHFFFAOYSA-N | SMILES = C=CC=C.[C-]#[O+].[C-]#[O+].[C-]#[O+].[Fe] }} |Section2={{Chembox Properties | C=7|H=6|Fe=1|O=3 | MolarMass = | Appearance = yellow oil | Density = | MeltingPtC = 19 | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }}(Butadiene)iron tricarbonyl is an organoiron compound with the formula (C{{sub|4}}H{{sub|6}})Fe(CO){{sub|3}}. It is the simplest and most studied metal complex of butadiene. It is an orange colored oil that freezes just below room temperature. The compound adopts a piano stool structure.[1] The complex was first prepared by heating iron pentacarbonyl with the diene.[2] Related compoundsIron(0) complexes of conjugated dienes have been extensively studied. In the butadiene series, (η{{sup|2}}-C{{sub|4}}H{{sub|6}})Fe(CO){{sub|4}} and (η{{sup|2}}:η{{sup|2}}-C{{sub|4}}H{{sub|6}})(Fe(CO){{sub|4}}){{sub|2}} have been crystallized.[3] Many related complexes are known for substituted butadienes and related species. The species (η{{sup|4}}-isoprene)iron tricarbonyl is chiral.[4] Cyclobutadieneiron tricarbonyl is a related complex. References1. ^{{cite journal|title=Redetermination of (η{{sup|4}}-s-cis-1,3-butadiene)tricarbonyliron(0)|author=Reiss, Guido J.|journal=Acta Crystallographica Section E|year=2010|volume=66|pages=m1369|doi=10.1107/S1600536810039218|pmc=3009352}} {{iron compounds}}{{DEFAULTSORT:Butadiene)iron tricarbonyl}}2. ^{{cite journal|title=Über Carbonyle und Nitrosyle. IV|pages=161–182|author1=Hans Reihlen|author2=A. Gruhl|author3=G. v. Heßling|author4=O. Pfrengle|doi=10.1002/jlac.19304820111|journal=Justus Liebigs Annalen der Chemie|year=1930|volume=482}} 3. ^{{cite journal|title=Butadien-Eisencarbonyl-Verbindungen (Butadieneiron Carbonyl Compounds)|author1=Murdoch, H. D.|author2=Weiss, E.|journal=Helvetica Chimica Acta|year=1962|volume=45|pages=1156–61|doi=10.1002/hlca.19620450412}} 4. ^{{cite journal|author=Grée, R.|title=Acyclic Butadiene-Iron Tricarbonyl Complexes in Organic Synthesis|year=1989|journal=Synthesis|doi=10.1055/s-1989-27250|pages=341–355}} 3 : Carbonyl complexes|Organoiron compounds|Half sandwich compounds |
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