“Diphosphorus tetroxide”的意思、由来-开放百科全书

Preparation

Phosphorus tetroxide is obtainable by thermal decomposition of phosphorus trioxide:

Phosphorus trioxide disproportionates above 210°C to form phosphorus and phosphorus tetroxide.

In addition, phosphorus trioxide can be converted into phosphorus tetroxide by controlled oxidation with oxygen in carbon tetrachloride solution.^[4]^[5]^[6]

Careful reduction of phosphorus pentoxide with red phosphorus at 450-525 °C also produces the phosphorus tetroxide.

References

1. ^http://www.wiley.com/college/math/chem/cg/sales/voet.html.
2. ^{{cite book|author=Alberts B.|year=2002|title= Molecular Biology of the Cell, 4th Ed.|publisher= Garland Science|isbn=978-0-8153-4072-0|display-authors=etal}}
3. ^{{cite book|author=Voet D., Voet J. G.|title=Biochemistry, 3rd Ed.|publisher= Wiley|isbn=978-0-471-19350-0|date=2004-03-09}}
4. ^{{cite book|author=Atkins P., de Paula J.|year=2006|title=Physical chemistry, 8th Ed.|publisher= W. H. Freeman|place= San Francisco|isbn= 978-0-7167-8759-4}}
5. ^{{cite book |last1 = Petrucci |first1 = Ralph H. |last2 = Harwood |first2 = William S. |last3 = Herring |first3 = F. Geoffrey |date=2002 |title = General chemistry: principles and modern applications |edition=8th |location=Upper Saddle River, N.J |publisher=Prentice Hall |isbn = 978-0-13-014329-7 |lccn=2001032331 |oclc=46872308 |ref=harv }}
6. ^{{cite book|author=Laidler K. J.|year=1978|title=Physical chemistry with biological applications. Benjamin/Cummings|place= Menlo Park|isbn= 978-0-8053-5680-9}}