“Draft:Calixpyrrole”的意思、由来-开放百科全书

Calixpyrroles, or calix[n]pyrroles, belong to a family of macrocyclic compounds consisting several pyrrole subunits. Calix[4]pyrrole was first synthesized by Baeyer in 1886

History

The first example of calixpyrroles can be traced back to 1886 when the German chemist, Adolf Baeyer, published the paper entitled "Ueber ein condensationsproduct von pyrrol mit aceton".^[1] In Baeyer's original paper, he reported the discovery of a new compound as the acid-catalyzed condensation product between pyrrole and acetone as well as its related properties. However, due to the limitation of the techniques,

Synthesis of Calix[n]pyrroles

Structure

Applications

Metal Complexation

Due to the resemblance of calix[4]pyrrole to porphyrin, the metal complexation was actually first investigated by the Floriani and co-workers.^[2]^[3]^[4]

Anion Binding

Ion-pair Receptor

References

1. ^{{Cite journal|last=Baeyer|first=Adolf|date=1886-07-01|title=Ueber ein Condensationsproduct von Pyrrol mit Aceton|url=https://onlinelibrary.wiley.com/doi/abs/10.1002/cber.188601902121|journal=Berichte der deutschen chemischen Gesellschaft|language=en|volume=19|issue=2|pages=2184–2185|doi=10.1002/cber.188601902121|issn=1099-0682}}
2. ^{{Cite journal|last=Rizzoli|first=Corrado|last2=Chiesi-Villa|first2=Angiola|last3=Floriani|first3=Carlo|last4=Jacoby|first4=Denis|date=1991-01-01|title=meso-Octamethyl-porphyrinogen metal complexes: an entry to high valent unsaturated metal centres|url=https://pubs.rsc.org/en/content/articlelanding/1991/c3/c39910000220|journal=Journal of the Chemical Society, Chemical Communications|language=en|volume=0|issue=4|pages=220–222|doi=10.1039/C39910000220|issn=0022-4936}}
3. ^{{Cite journal|last=Rizzoli|first=Corrado|last2=Chiesi-Villa|first2=Angiola|last3=Floriani|first3=Carlo|last4=Jacoby|first4=Denis|date=1991-01-01|title=The π and σ bonding modes of meso-octaethylporphyrinogen to transition metals: the X-ray structure of a meso-octaethylporphyrinogen–zirconiuml(IV) complex and of the parent meso-octaethylporphyrinogen ligand|url=https://pubs.rsc.org/en/content/articlelanding/1991/c3/c39910000790|journal=Journal of the Chemical Society, Chemical Communications|language=en|volume=0|issue=11|pages=790–792|doi=10.1039/C39910000790|issn=0022-4936}}
4. ^{{Cite journal|last=Jacoby|first=Denis|last2=Isoz|first2=Sylviane|last3=Floriani|first3=Carlo|last4=Chiesi-Villa|first4=Angiola|last5=Rizzoli|first5=Corrado|date=1995-03-01|title=Electrophilic Activation of Aliphatic C-H Bonds Mediated by Zirconium Hydride Entities and Applied to the Functionalization of the Porphyrinogen Periphery|url=https://doi.org/10.1021/ja00115a015|journal=Journal of the American Chemical Society|volume=117|issue=10|pages=2805–2816|doi=10.1021/ja00115a015|issn=0002-7863}}