| 词条 | 1-Bromohexane |
| 释义 |
| Watchedfields = changed | verifiedrevid = 477207159 | ImageFile = 1-Bromohexane-3D-balls.png | ImageFile_Ref = {{chemboximage|correct|??}} | ImageSize = 160 | ImageName = Ball and stick model of 1-bromohexane | ImageFile1 = 1-Bromohexane-3D-spacefill.png | ImageFile1_Ref = {{chemboximage|correct|??}} | ImageSize1 = 160 | ImageName1 = Spacefill model of 1-bromohexane | IUPACName = 1-Bromohexane[1] | OtherNames = {{Unbulleted list|Bromohexane{{Citation needed|date=June 2012}}|Hexyl bromide{{Citation needed|date=June 2012}}|1-Hexyl bromide{{Citation needed|date=June 2012}}|n-Hexyl bromide{{Citation needed|date=June 2012}} }} |Section1={{Chembox Identifiers | CASNo = 111-25-1 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 8101 | ChemSpiderID = 7810 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | EINECS = 203-850-2 | UNNumber = 1993 | MeSHName = 1-bromohexane | RTECS = MO0925000 | Beilstein = 1731290 | SMILES = CCCCCCBr | StdInChI = 1S/C6H13Br/c1-2-3-4-5-6-7/h2-6H2,1H3 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = MNDIARAMWBIKFW-UHFFFAOYSA-N | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} }} |Section2={{Chembox Properties | C=6 | H=13 | Br=1 | Appearance = Colorless liquid | Density = 1.176 g/mL | MeltingPtK = 188.45 | BoilingPtK = 427 to 431 | RefractIndex = 1.448 | Solubility = Insoluble | SolubleOther = Alcohol, ether{{cn|date=November 2012}} }} |Section3={{Chembox Thermochemistry | DeltaHf = −196.1–−192.9 kJ mol−1 | DeltaHc = −4026.2–−4023.0 kJ mol−1 | Entropy = 452.92 J K−1 mol−1 | HeatCapacity = 219.7 J K−1 mol−1 }} |Section4={{Chembox Hazards | GHSPictograms = {{GHS flame}} {{GHS exclamation mark}} | GHSSignalWord = WARNING | HPhrases = {{H-phrases|226|315|319|335}} | PPhrases = {{P-phrases|261|305+351+338}} | FlashPtC = 57 | NFPA-H = 1 | NFPA-F = 2 | NFPA-R = 0 | LD50 = 1.226 g/kg (IP, mouse) }} |Section5={{Chembox Related | OtherFunction_label = alkanes | OtherFunction = {{Unbulleted list|1-Bromobutane|2-Bromobutane|2-Bromohexane}} }} }} 1-Bromohexane is a liquid organohalide with structural formula Br-CH2-CH2-CH2-CH2-CH2-CH3. Its refractive index is 1.4478 (20 °C, D). ApplicationsIt is used to manufacture pharmaceuticals and organic chemicals. 1-Bromohexane is also a solvent that is frequently used in grignard reactions, that are involved with creating bromo-cyclic compounds. [2] See also
References1. ^{{Cite web|title=1-bromohexane - Compound Summary|url=https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=8101|work=PubChem Compound|publisher=National Center for Biotechnology Information|accessdate=17 June 2012|location=USA|date=26 March 2005|at=Identification}} {{Organohalide-stub}}{{DEFAULTSORT:Bromohexane, 1-}}2. ^Garst, J., Ungvary, F., Batlaw, R., & Lawrence, K. (1991). Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. Journal of American Chemical Society, 113(14), 5392-5397. 1 : Bromoalkanes |
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