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词条 1-Butene
释义

  1. Reactions

  2. Manufacturing

  3. See also

  4. References

  5. External links

{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477207214
| ImageFileL1 = But-1-ene-2D-skeletal.png
| ImageSizeL1 = 130px
| ImageFileR1 =But-1-ene-3D-balls.png
| ImageSizeR1 = 130px
| ImageFile1 = 1-butene.svg
| ImageSize = 130px
| PIN = But-1-ene[1]
| OtherNames = Ethylethylene
1-Butylene
α-Butylene
| Section1 = {{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 48362
| ChemSpiderID = 7556
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 117210
| InChI = 1/C4H8/c1-3-4-2/h3H,1,4H2,2H3
| InChIKey = VXNZUUAINFGPBY-UHFFFAOYAZ
| SMILES1 = CCC=C
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C4H8/c1-3-4-2/h3H,1,4H2,2H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VXNZUUAINFGPBY-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 106-98-9
| PubChem = 7844
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = LY001N554L
| SMILES = C=CCC
}}
| Section2 = {{Chembox Properties
| C=4 | H=8
| Appearance = Colorless Gas
| Odor = slightly aromatic
| Density = 0.62 g/cm3
| MeltingPtC = -185.3
| BoilingPtC = -6.47
| Solubility = 0.221 g/100 mL
| SolubleOther = soluble in alcohol, ether, benzene
| RefractIndex = 1.3962
| Viscosity = 7.76 Pa
| Section3 = {{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPtC = 385
| ExploLimits = 1.6-10%
| NFPA-H = 1 | NFPA-F = 4 | NFPA-R = 0
}}
}}

1-Butene is an organic chemical compound, linear alpha-olefin (alkene),[2] and one of the isomers of butene. The formula is CH3CH2CH=CH2. It is a highly flammable, easily condensed gas.

Reactions

1-Butene is stable in itself but polymerizes readily to polybutene. Its main application is as a comonomer in the production of certain kinds of polyethylene, such as linear low-density polyethylene (LLDPE). It has also been used as a precursor to polypropylene resins, butylene oxide, and butanone.[3]

Manufacturing

1-Butene is produced by separation from crude C4 refinery streams and by ethylene dimerization. The former affords a mixture of 1-and 2-butenes, while the latter affords only the terminal alkene.[4] It is distilled to give a very high-purity product. An estimated 12 billion kilograms were produced in 2011.[5]

See also

  • Butene
  • Dimer (chemistry)
  • Octene

References

1. ^{{cite book | title = Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book) | publisher = The Royal Society of Chemistry | date = 2014 | location = Cambridge | pages = 17, 61, 374 | doi = 10.1039/9781849733069-FP001 | isbn = 978-0-85404-182-4}}
2. ^{{cite web|url=http://chemicalland21.com/industrialchem/organic/1-BUTENE.htm|title=1-BUTENE|author=|date=|website=chemicalland21.com|accessdate=22 April 2018}}
3. ^{{cite web|url=http://www.shell.com/home/content/chemicals/products_services/our_products/lower_olefins/1_butene/product_overview/|title=1-Butene product overview|author=|date=|website=shell.com|accessdate=22 April 2018|archive-url=https://web.archive.org/web/20120210001059/http://www.shell.com/home/content/chemicals/products_services/our_products/lower_olefins/1_butene/product_overview/|archive-date=2012-02-10|dead-url=yes|df=}}
4. ^{{cite web|url=http://chempedia.info/info/151339/|title=Alphabutol process - Big Chemical Encyclopedia|author=|date=|website=chempedia.info|accessdate=22 April 2018|archive-url=https://web.archive.org/web/20171208231536/http://chempedia.info/info/151339/|archive-date=2017-12-08|dead-url=yes|df=}}
5. ^{{cite encyclopedia|last1=Geilen|first1=Frank M.A.|last2=Stochniol|first2=Guido|last3=Peitz|first3=Stephan|last4=Schulte-Koerne|first4=Ekkehard|title=Butenes|encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry|publisher=Wiley-VCH|place=Weinheim|year=2014|doi=10.1002/14356007.a04_483.pub3}}

External links

  • 1-Butene {{chem|C|4|H|8}}
{{Hydrides by group}}{{DEFAULTSORT:Butene, 1-}}Buteno#El 1-buteno

1 : Alkenes

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