词条 | 1-Butene |
释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 477207214 | ImageFileL1 = But-1-ene-2D-skeletal.png | ImageSizeL1 = 130px | ImageFileR1 =But-1-ene-3D-balls.png | ImageSizeR1 = 130px | ImageFile1 = 1-butene.svg | ImageSize = 130px | PIN = But-1-ene[1] | OtherNames = Ethylethylene 1-Butylene α-Butylene | Section1 = {{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = 48362 | ChemSpiderID = 7556 | ChEMBL_Ref = {{ebicite|correct|EBI}} | ChEMBL = 117210 | InChI = 1/C4H8/c1-3-4-2/h3H,1,4H2,2H3 | InChIKey = VXNZUUAINFGPBY-UHFFFAOYAZ | SMILES1 = CCC=C | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C4H8/c1-3-4-2/h3H,1,4H2,2H3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = VXNZUUAINFGPBY-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 106-98-9 | PubChem = 7844 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = LY001N554L | SMILES = C=CCC }} | Section2 = {{Chembox Properties | C=4 | H=8 | Appearance = Colorless Gas | Odor = slightly aromatic | Density = 0.62 g/cm3 | MeltingPtC = -185.3 | BoilingPtC = -6.47 | Solubility = 0.221 g/100 mL | SolubleOther = soluble in alcohol, ether, benzene | RefractIndex = 1.3962 | Viscosity = 7.76 Pa | Section3 = {{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPtC = 385 | ExploLimits = 1.6-10% | NFPA-H = 1 | NFPA-F = 4 | NFPA-R = 0 }} }} 1-Butene is an organic chemical compound, linear alpha-olefin (alkene),[2] and one of the isomers of butene. The formula is CH3CH2CH=CH2. It is a highly flammable, easily condensed gas. Reactions1-Butene is stable in itself but polymerizes readily to polybutene. Its main application is as a comonomer in the production of certain kinds of polyethylene, such as linear low-density polyethylene (LLDPE). It has also been used as a precursor to polypropylene resins, butylene oxide, and butanone.[3] Manufacturing1-Butene is produced by separation from crude C4 refinery streams and by ethylene dimerization. The former affords a mixture of 1-and 2-butenes, while the latter affords only the terminal alkene.[4] It is distilled to give a very high-purity product. An estimated 12 billion kilograms were produced in 2011.[5] See also
References1. ^{{cite book | title = Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book) | publisher = The Royal Society of Chemistry | date = 2014 | location = Cambridge | pages = 17, 61, 374 | doi = 10.1039/9781849733069-FP001 | isbn = 978-0-85404-182-4}} 2. ^{{cite web|url=http://chemicalland21.com/industrialchem/organic/1-BUTENE.htm|title=1-BUTENE|author=|date=|website=chemicalland21.com|accessdate=22 April 2018}} 3. ^{{cite web|url=http://www.shell.com/home/content/chemicals/products_services/our_products/lower_olefins/1_butene/product_overview/|title=1-Butene product overview|author=|date=|website=shell.com|accessdate=22 April 2018|archive-url=https://web.archive.org/web/20120210001059/http://www.shell.com/home/content/chemicals/products_services/our_products/lower_olefins/1_butene/product_overview/|archive-date=2012-02-10|dead-url=yes|df=}} 4. ^{{cite web|url=http://chempedia.info/info/151339/|title=Alphabutol process - Big Chemical Encyclopedia|author=|date=|website=chempedia.info|accessdate=22 April 2018|archive-url=https://web.archive.org/web/20171208231536/http://chempedia.info/info/151339/|archive-date=2017-12-08|dead-url=yes|df=}} 5. ^{{cite encyclopedia|last1=Geilen|first1=Frank M.A.|last2=Stochniol|first2=Guido|last3=Peitz|first3=Stephan|last4=Schulte-Koerne|first4=Ekkehard|title=Butenes|encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry|publisher=Wiley-VCH|place=Weinheim|year=2014|doi=10.1002/14356007.a04_483.pub3}} External links
1 : Alkenes |
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