| 词条 | 1-Butyl-3-methylimidazolium hexafluorophosphate |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 477199310 | ImageFile = ILfromOS.svg | ImageSize = 220 | ImageFile1 = BMIM-PF6-3D-balls.png | ImageSize1 = 220 | ImageAlt1 = BMIM cation and PF6 anion | IUPACName=1-butyl-3-methylimidazol-3-ium hexafluorophosphate | OtherNames= BMIM-PF6 |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 2015930 | InChI = 1/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1 | SMILES1 = CCCCn1cc[n+](c1)C.F[P-](F)(F)(F)(F)F | InChIKey = IXQYBUDWDLYNMA-UHFFFAOYAH | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = IXQYBUDWDLYNMA-UHFFFAOYSA-N | CASNo_Ref = {{cascite|changed|??}} | CASNo= 174501-64-5 | PubChem=2734174 | SMILES= CCCCN1C=C[N+](=C1)C.F[P-](F)(F)(F)(F)F |Section2={{Chembox Properties | Solvent = | C=8 | H=15 | F=6 | N=2 | P=1 | Appearance= Light yellow liquid | Density= 1.38 g/mL (20 °C) | MeltingPtC= -8 | BoilingPtC= | Solubility=insoluble |Section3={{Chembox Hazards | MainHazards= | FlashPt= | AutoignitionPt = }}1-Butyl-3-methylimidazolium hexafluorophosphate, also known as BMIM-PF6, is a viscous, colourless, hydrophobic and non-water-soluble ionic liquid with a melting point[1] of -8 °C. Together with 1-butyl-3-methylimidazolium tetrafluoroborate, BMIM-BF4, it is one of the most widely studied ionic liquids. It is known to very slowly decompose in the presence of water.[2] PreparationBMIM-PF6 is commercially available. It may be obtained in two steps: BMIM-Cl is synthesized by alkylating 1-methylimidazole with 1-chlorobutane. A metathesis reaction with potassium hexafluorophosphate gives the desired compound; the tetrafluoroborate may be prepared by analogously using potassium tetrafluoroborate.[3] See also
References1. ^{{cite book|url=https://books.google.com/books?id=y8d9F7NG60cC&lpg=PR28&pg=PR27|page=xxvii|title=Ionic Liquids in Chemical Analysis|author=Mihkel Koel|publisher=CRC Press|year=2008|isbn=1-4200-4646-2}} 2. ^{{cite journal |author1=R.P. Swatloski |author2=J.D. Holbrey |author3=R.D. Rogers |lastauthoramp=yes | title = Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate | journal = Green Chem. | year = 2003 | volume = 5 | pages = 361–363 | doi = 10.1039/b304400a | issue = 4}} 3. ^{{OrgSynth | vauthors = Dupont J, Consorti C, Suarez P, de Souza R | title = Preparation of 1-Butyl-3-methyl imidazolium-based Room Temperature Ionic Liquids | collvol = 10 | collvolpages = 184 | year = 2004 | prep = v79p0236}} Further reading
3 : Hexafluorophosphates|Imidazoles|Ionic liquids |
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