| 词条 | Iridium tetrachloride |
| 释义 |
| ImageFile = | ImageSize = | ImageAlt = | IUPACName = | OtherNames = |Section1={{Chembox Identifiers | CASNo = 10025-97-5 | PubChem = 24815 | ChemSpiderID=11252181 | EC_number = 233-048-8 | UNII = PCG7KVC21I | InChI=1S/4ClH.Ir/h4*1H;/q;;;;+4/p-4 | InChIKey=CALMYRPSSNRCFD-UHFFFAOYSA-J | SMILES = Cl[Ir](Cl)(Cl)Cl}} |Section2={{Chembox Properties | Ir=1|Cl=4 | MolarMass = | Appearance = amorphous brown solid | Density = | MeltingPt = | BoilingPt = | Solubility = good}} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }}Iridium tetrachloride is an inorganic compound with the approximate formula IrCl4(H2O)n. It is a water-soluble dark brown amorphous solid. A well defined derivative is ammonium hexachloroiridate ((NH4)2IrCl6).[1] It is used to prepare catalysts, such as the Henbest Catalyst for transfer hydrogenation of cyclohexanones.[2] References1. ^{{cite journal|title=Iridium(IV) Chloride|author=Thomas R. B. Mitchell|year=2001|doi=10.1002/047084289X.ri050|journal=e-EROS Encyclopedia of Reagents for Organic Synthesis}} {{Iridium compounds}}2. ^{{cite journal|journal=Org. Synth.|year=1970|volume=50|page=13|doi=10.15227/orgsyn.050.0013|title=cis-4-tert-Butylecyclohexanol|authors=E. L. Eliel, T. W. Doyle, R. O. Hutchins, E. C. Gilbert}} 2 : Iridium compounds|Chloro complexes |
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