“2,4,6-Tris(trinitromethyl)-1,3,5-triazine”的意思、由来-开放百科全书

词条

2,4,6-Tris(trinitromethyl)-1,3,5-triazine

释义

References

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 477191519
| Name = 2,4,6-Tris(trinitromethyl)-1,3,5-triazine
| ImageFile = TTNMTZ.svg
| ImageSize = 180
| ImageAlt = 2,4,6-Tris(trinitromethyl)-1,3,5-triazine
| ImageFile1 = 2,4,6-Tris(trinitromethyl)-1,3,5-triazine-3D-balls.png
| ImageSize1 = 180
| ImageAlt1 = Ball-and-stick model of the 2,4,6-tris(trinitromethyl)-1,3,5-triazine molecule
| IUPACName = 2,4,6-Tris(trinitromethyl)-1,3,5-triazine
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 161870-33-3
| InChIKey = MTNISTQLDNOGTM-UHFFFAOYAO
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = MTNISTQLDNOGTM-UHFFFAOYSA-N
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 9664224
| InChI = 1/C6N12O18/c19-10(20)4(11(21)22,12(23)24)1-7-2(5(13(25)26,14(27)28)15(29)30)9-3(8-1)6(16(31)32,17(33)34)18(35)36
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C6N12O18/c19-10(20)4(11(21)22,12(23)24)1-7-2(5(13(25)26,14(27)28)15(29)30)9-3(8-1)6(16(31)32,17(33)34)18(35)36
| SMILES = O=[N+]([O-])C(c1nc(nc(n1)C([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O)C([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O
}}
|Section2={{Chembox Properties
| C=6|N=12|O=18
| Density = 1.91 g/cm³
| MeltingPtC = 91 to 92
| MeltingPt_notes =
| BoilingPt =
|Section8={{Chembox Related
| OtherCompounds = 4,4’-Dinitro-3,3’-diazenofuroxan
Hexanitrohexaazaisowurtzitane
Heptanitrocubane
Octanitrocubane
}}

2,4,6-Tris(trinitromethyl)-1,3,5-triazine is a chemical compound that is a derivative of triazine first prepared in 1995.^[1] It is synthesized by destructive nitration of 2,4,6-tricarboxyl-1,3,5-triazine. It is noteworthy for having more nitro groups than it does carbon atoms, so could be used as an oxygen source, or added to oxygen-poor explosives to increase their power.

Derivatives have been prepared by nucleophilic displacement of the nitro groups with azide and hydrazine.^[2]

References

1. ^{{cite journal | doi = 10.1070/MC1995v005n01ABEH000440| title = Synthesis of 2,4,6-Tris(trinitromethyl)-1,3,5-triazine| journal = Mendeleev Communications| volume = 5| pages = 17| year = 1995| last1 = Shastin| first1 = Alexey V.| last2 = Godovikova| first2 = Tamara I.| last3 = Golova| first3 = Svetlana P.| last4 = Kuz'Min| first4 = Vladimir S.| last5 = Khmel'Nitskii| first5 = Lenor I.| last6 = Korsunskii| first6 = Boris L.}}
2. ^{{cite journal | doi = 10.1023/A:1023970928207| year = 2003| last1 = Shastin| first1 = A. V.| journal = Chemistry of Heterocyclic Compounds| volume = 39| issue = 3| pages = 354 | title = Nucleophilic Substitution Reactions of 2,4,6-Tris(trinitromethyl)-1,3,5-triazine. 3. Reaction of 2,4,6-Tris(trinitromethyl)-1,3,5-triazine with Azides and Hydrazine}}

3 : Triazines|Nitro compounds|Explosive chemicals

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