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词条 Methylene imine
释义

  1. References

{{Chembox
| ImageFile = Methanimine.png
| ImageSize = 144
| ImageAlt =
| IUPACName =
| OtherNames = formaldimine, azomethine, formaldehyde imine, methanimine
|Section1={{Chembox Identifiers
| CASNo = 2053-29-4
| PubChem = 123139
| ChEBI = 38220
| ChemSpiderID = 109754
| Gmelin = 163896
| Beilstein = 1900196
| StdInChI=1S/CH3N/c1-2/h2H,1H2
| StdInChIKey = WDWDWGRYHDPSDS-UHFFFAOYSA-N
| SMILES = C=N
|Section2={{Chembox Properties
| C=1|H=3|N=1
| MolarMass =
| Appearance = colorless gas
| Density =
| MeltingPt =
| MeltingPt_notes =
| BoilingPt =
| Solubility = }}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
}}

Methylene imine is an organic compound with the formula CH2NH. It is the simplest imine, a class of compounds with C=N double bonds. It is a stable colorless gas that has been detected throughout the universe.[1] Unhindered imines polymerize or oligomerize when concentrated. Thus, methylene imine has not been isolated as a liquid or bulk solid, instead attempted synthesis of methylene imine from the reaction of ammonia and formaldehyde affords hexamethylenetetramine.

[2]

References

1. ^{{cite journal|title=The nitrogen chemistry of Titan's upper atmosphere revealed|last1=Vuitton |first1= V. |last2=Yelle |first2= R. V. |last3= Anicich |first3=V. G.|journal=Astrophysical Journal|year=2006|volume=647|pages=L175-L178|doi=10.1086/507467}}
2. ^{{cite encyclopedia | title=Amines, Aliphatic | encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry | publisher=Wiley-VCH Verlag GmbH | year=2000 | isbn=9783527306732 | doi=10.1002/14356007.a02_001 | last1=Eller | last2=Henkes | last3=Rossbacher | last4=Höke | first1=K. | first2=E. | first3=R. | first4=H.}}

1 : Imines

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