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词条 Nickel ternary chalcogenides
释义

  1. References

The Nickel ternary chalcogenides are a class of chemical compounds that contains nickel, a chalcogenide, and another element. Nickel forms a series of double nickel oxides with other elements, which may be termed "nickelates". These double nickel oxides are not listed on this page. There are also many well defined double compounds with sulfur, selenium and tellurium which are listed here.

formulanamecolourstructureproductionreferences
NH4NiS5ammonium nickel sulphideblackNH4 polysulfide+NiSO4[1][1]
K2Ni3S4potassium nickel tetrasulfidebronze yellowFddd a=10.023 b=26.074 c=5.704NiSO4 K2CO3 S[1][2][3]
K2Ni11S10potassium nickel decasulfidedark metallic greenNiO+KCNS[4] J. Milbauer
Na2Ni3S4sodium nickel tetrasulfidedark yellowNiSO4 Na2CO3 S[4] R. Schneider
KNi2S2potassium dinickel disulfideorange yellowNi foil, S, K at 723K[5][6]
K2Ni3Se4potassium nickel tetraselenidegoldFddd a=10.468 b=26.496 c=5.995[7][11]
KNi2Se2potassium dinickel diselenidepurple-redI4/mmmtetragonal a=3.909, c=13.4142Ni foil, Se shot, K at 723K[5][8]
CsNi2Se2caesium dinickel diselenidetetragonal a=3.988, c=14.419heat elements[9]
TlNi2Se2Thallium dinickel diselenidegold metallictetragonalheat elements together in closed quartz tube[10]
Rb2Ni3S4rubidium nickel tetrasulphidemetallic greenish goldFmmm orthorhombic a=9.901 Å, b=13.606 Å and c=5.861 Z=4 layered; ferromagnetic only after water immersion[7][11]
Rb2Ni3Se4rubidium nickel tetraselenidegolden metallicFddd orthorhombic a = 10.555 Å, b = 27.588 Å, c = 6.031 Å, Z = 8 layered; ferromagnetic only after water immersionRb2CO3 S Ni[12]
Cs2Ni3S4cesium nickel tetrasulphidegreenish goldFmmm a=10.038 b=14.552 c=5.934[11][12]
Cs2Ni3S4cesium nickel tetrasulphidegoldFmmm a=10.540 b=14.624 c=6.194[13]
Cs0.9Ni3.1Se3Hexagonal P63/m a = 9.26301(4) Å and c = 4.34272(2) Åquasi-one-dimensional electric conductor[14]
BaNi4S5Barium nickel pentasulfidebronze yellowNiSO4 K2CO3 S[4] R. Schneider; I. and L. Bellucci
Pb2Ni3S2lead nickel disulfidemelt 790°PbS Ni[15] W Guertler; W Guertler H Schack
(Ni,Fe)9S8Pentlanditebronze yellow melt 870[15] T. Scheerer
Fe2Ni2S4ferrous nickel tetrasulfidemelt 840[16] K Bornemann
Fe2Ni2S3ferrous nickel trisulfidestable over 575°, melt 886,[17] K Bornemann
Fe3Ni4S5ferrous nickel pentasulfidebelow 575[17] K Bornemann
Fe4Ni2S5[17] K Bornemann
Fe2Ni3S4[17] K Bornemann
Fe3Ni4S5[17] K Bornemann
Fe2Ni2S3[17] K Bornemann
FeNi2S4Violaritedark violet greymineral oxidate
Ni3Sn2S2[18]
Ni3Bi2S2superconducting[18]
Ni3Bi2Se2superconducting[18]
NiSnS3nickel thiostannategreenish blackorthorhombic a=6.88 b=7.89 c=11.95 Z=8 V=644NiCl2 + SnS2[19]
NiGeS33nickelselenogermanate[20]
Ta2NiS5Orthorhombic[21]
Ta2NiSe5monoclinic β=90.53[21]
Ta2Ni2Te4[22]
Ta2Ni3Te5[22]

References

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4. ^Mellor p443
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15. ^Mellor p444
16. ^Mellor p445
17. ^Mellor p446
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2 : Nickel compounds|Chalcogenides

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