| 词条 | Pentachlorobenzenethiol |
| 释义 |
| ImageFile = Pentachlorbenzolthiol.svg | ImageSize = 200px | ImageAlt = | IUPACName = 2,3,4,5,6-pentachlorobenzenethiol | OtherNames = Pentachlorobenzenethiol, pentachlorothiophenol, PCBT | Section1 = {{Chembox Identifiers | CASNo = 133-49-3 | PubChem = 8620 | ChemSpiderID = 8301 | EINECS = 205-107-8 | SMILES = C1(=C(C(=C(C(=C1Cl)Cl)Cl)Cl)Cl)S | StdInChI= 1S/C6HCl5S/c7-1-2(8)4(10)6(12)5(11)3(1)9/h12H | StdInChIKey= LLMLGZUZTFMXSA-UHFFFAOYSA-N | Section2 = {{Chembox Properties | C=6|H=1|Cl=5|S=1 | Appearance = Gray solid | Density = 1.7±0.1 g/cm3 | Solubility = Insoluble | MeltingPtC = 231.5 | BoilingPtC = | VaporPressure = | Section3 = {{Chembox Hazards | MainHazards = | GHSPictograms = {{GHS05}} | GHSSignalWord = WARNING | HPhrases = | PPhrases = | FlashPtC = 144.6 | AutoignitionPt = }}Pentachlorobenzenethiol is a chemical compound from the group of thiols and organochlorine compounds.[1] The chemical formula is {{chem|C|6|H|Cl|5|S}}.[2] SynthesisPentachlorobenzenethiol can be obtained from hexachlorobenzene.[3] PropertiesPentachlorobenzenethiol is a combustible gray solid with an unpleasant odor, practically insoluble in water. It has a monoclinic crystal structure.[4] The compound is not well-biodegradable and presumably bioaccumulable and toxic for aquatic organisms. Pentachlorobenzenethiol is itself a metabolite of hexachlorobenzene and is found in the urine and the excretions of animals receiving hexachlorobenzene.[5] Pentachlorobenzenethiol has a high potential for long-range transport via air as it is very slowly degraded in atmosphere.[6] ApplicationsPentachlorobenzenethiol is used in the rubber industry. The compound is added to rubber (both natural and synthetic) to facilitate processing (mastication). See also
References1. ^{{cite web|title=Pentachlorobenzenethiol|url=http://www.chemindustry.com/chemicals/0268505.html|publisher=chemindustry.com|accessdate=9 June 2017}} 2. ^{{cite web|title=2,3,4,5,6-pentachlorobenzenethiol|url=http://www.chemsynthesis.com/base/chemical-structure-23939.html|accessdate=9 June 2017}} 3. ^{{cite journal|last1=Gates|first1=B. C.|last2=Webber|first2=K. M.|title=Pentachlorobenzenethiol: A new promotor for the Rh(I)-complex-catalyzed methanol carbonylation|journal=Journal of Catalysis|date=May 1977|volume=47|issue=2|pages=269–271|doi=10.1016/0021-9517(77)90174-9|url=http://www.sciencedirect.com/science/article/pii/0021951777901749|accessdate=9 June 2017}} 4. ^{{cite journal|last1=Wojcik|first1=G.|last2=Charbonneau|first2=G. P.|last3=Delugeard|first3=Y.|last4=Toupet|first4=L.|title=The disordered crystal structure of pentachlorothiophenol|journal=Acta Crystallogr.|date=1980|volume=B36|issue=2|pages=506–507|doi=10.1107/S0567740880003706|url=http://scripts.iucr.org/cgi-bin/paper?S0567740880003706|accessdate=9 June 2017}} 5. ^{{cite journal|last1=Koss|first1=G.|last2=Koransky|first2=W.|last3=Steinbach|first3=K.|title=Studies on the toxicology of hexachlorobenzene: II. Identification and determination of metabolites.|journal=Archives of Toxicology|date=June 1976|volume=35|issue=2|pages=107–114|doi=10.1007/BF00372764}} 6. ^{{cite web|title=TC NES SUBGROUP ON IDENTIFICATION OF PBT AND VPVB SUBSTANCES|url=https://echa.europa.eu/documents/10162/be8c1c49-af6e-4b6f-9927-b4e1bc7f50f5|website=EChA|publisher=echa.europa.eu|accessdate=9 June 2017}} External links
3 : Benzene derivatives|Thiols|Organochlorides |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。