| 词条 | Phosphirane |
| 释义 |
| ImageFile = Phosphirane.png | ImageSize = 144 | ImageAlt = | PIN = Phosphirane | OtherNames = Phosphacyclopropane Phosphiran |Section1={{Chembox Identifiers | CASNo = 6569-82-0 | PubChem = | ChemSpiderID = 10451470 | InChI=1S/C2H5P/c1-2-3-1/h3H,1-2H2 | InChIKey = UTMQOVWWMLZKRY-UHFFFAOYSA-N | SMILES = C1PC1 }} |Section2={{Chembox Properties | C=2|H=5|P=1 | MolarMass = | Appearance = colorless gas | Density = | MeltingPtC = −121 | BoilingPtC = 36.5 | BoilingPt_ref = [1] | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }} Phosphirane is the organophosphorus compound with the formula C2H4PH. It is a colorless gas of no commercial value. As the simplest cyclic, saturated organophosphorus compound, phosphirane is the prototype of a family of related compounds that have attracted attention from the research community. Phosphirane was first prepared by reaction of 1,2-dichloroethane with the conjugate base of phosphine.[2] Phosphiranes, that is substituted phosphirene compounds where one or more of the H's are replaced organic substituents, are far more commonly discussed than the parent phosphirane. References1. ^{{cite journal |last1=Wagner |first1=Ross I. |last2=Freeman |first2=LeVern D. |last3=Goldwhite |first3=H. |last4=Rowsell |first4=D. G. |title=Phosphiran |journal=Journal of the American Chemical Society |date=March 1967 |volume=89 |issue=5 |pages=1102–1104 |doi=10.1021/ja00981a013}} 2. ^{{cite encyclopedia|encyclopedia=Comprehensive Heterocyclic Chemistry II|year=1996|pages=277–304|volume=1A|title=Phosphiranes, Phosphirenes, and Heavier Analogues|authors=François Mathey, Manfred Regitz|doi=10.1016/B978-008096518-5.00008-3}}
External links 2 : Phosphorus heterocycles|Three-membered rings |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。