| 词条 | Ruthenium(III) acetate |
| 释义 |
|Watchedfields=changed |verifiedrevid= |ImageFile=BasicRuAcetateBF4dihydrate.png |Name=Ruthenium(III) acetate |IUPACName= |OtherNames= |Section1={{Chembox Identifiers | SMILES = | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = | PubChem = | InChI = | InChIKey = | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = | CASNo_Ref = {{cascite|correct|??}} | CASNo = | RTECS = |Section2={{Chembox Properties | C = 12 | H = 28 | Ru = 3 | O = 18|F=4|B=1 | Appearance = green solid | Density = 2.110 g/cm3 | Solubility = | MeltingPt = | MagSus = | MolShape = | Coordination = octahedral | CrystalStruct = | Dipole = | ExternalSDS = | MainHazards = | RPhrases = | SPhrases = | OtherCompounds = Manganese(III) acetate Iron(III) acetate Ruthenium(III) acetate, commonly known as basic ruthenium acetate,[1] describes a family of salts where the cation has the formula [Ru3O(O2CCH3)6(OH2)3]+. A representative derivative is the dihydrate of the tetrafluoroborate salt [Ru3O(O2CCH3)6(OH2)3]BF4(H2O)2, which is the source of the data in the table above.[2] This and related salts are forest green, air-stable solids that are soluble in alcohols. Basic ruthenium acetate features octahedral Ru(III) centers, a triply bridging oxo ligand, six acetate ligands, and three aquo ligands. The same structure is shared with basic acetates of iron, chromium, iridium, and manganese.[1][2] Preparation and reactionsIt is prepared by heating ruthenium trichloride in acetic acid in the presence of sodium acetate.[3] The basic acetates of ruthenium were reported in the early 1950's but were not properly formulated.[4] Basic ruthenium acetate reacts with many ligands such as triphenylphosphine and pyridine concomitant with reduction. These derivatives [Ru3O(O2CCH3)6L3]0 are mixed valence compounds.[5] References1. ^1 {{Greenwood&Earnshaw2nd}} {{Acetates}}2. ^1 {{cite journal|authors=O. Almog, A. Bino, D. Garfinkel-Shweky|journal=Inorg. Chim. Acta|year=1993|volume=213|title=The Structure of Oxo-Bridged Trinuclear Ruthenium and Iridium Hexacarboxylates|doi=10.1016/S0020-1693(00)83819-0|page=99}} 3. ^{{cite book|title=Basic Ruthenium Acetate and Mixed Valence Derivatives|authors=J. C. Goeltz, S. D. Glover, J. Hauk, C. P. Kubiak|journal=Inorg. Synth.|year=2010|volume=35|pages=156–160|doi=10.1002/9780470651568.ch8|series=Inorganic Syntheses|isbn=9780470651568}} 4. ^{{cite journal|title=Basic Trinuclear Ruthenium Acetate|author= Martin, F. S.|journal=Journal of the Chemical Society|year=1952|pages=2682–4|doi=10.1039/jr9520002682}} 5. ^{{cite journal|authors=Cotton, F. A.; Norman, J. G., Jr.|title=Structural Characterization of a Basic trinuclear Ruthenium Acetate|journal=Inorg. Chim. Acta |year=1972|volume=6|pages=411–419|doi=10.1016/S0020-1693(00)91829-2}} 2 : Ruthenium compounds|Acetates |
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