| 词条 | Solvated metal atom dispersion |
| 释义 |
Solvated Metal Atom Dispersion is a method of producing highly reactive solvated nanoparticles. Samples of the metal (or ceramic) are heated to produce free atoms (or species), as in PVD evaporation. These are then co-depositied with a suitable organic frozen solvent (e.g. toluene)[3] at very low temperatures (on the order of 70K).[4] This is then warmed towards room temperature, producing solvated metal ions or (over time) larger clusters. Sometimes, catalysts supports (such as SiO2 or Al2O3) are added to improve nucleation,[5] as it can more readily take place on surface OH groups. References1. ^1 {{cite journal | last1 = Klabunde | first1 = Kenneth J. | title = Solvated Atoms of Platinum, Palladium and Gold — Precursors to Colloids, Films and Catalysts | journal = Platinum Metals Review | volume = 36 | pages = 80–84 | date = 1992 | url = https://www.technology.matthey.com/wp-content/uploads/pdf/pmr-v36-i2-080-084.pdf | issn =0032-1400 }} [1][2][3]2. ^1 {{cite book |last1=Schubert |first1=Ulrich|last2=Hüsing |first2=Nicola |date=March 2012 |chapter=7|chapter-url=http://folk.uio.no/ravi/cutn/scm/synthesis/chap%207.pdf|title=Synthesis of Inorganic Materials, 3rd Edition|url=https://books.google.com/books/about/Synthesis_of_Inorganic_Materials.html?id=zTYvAQAAIAAJ |url-access=limited|language=English|edition=Third|publisher=Wiley|pages=370–375|isbn=978-3-527-32714-0}} 3. ^1 {{cite journal | last1 = Klabunde | first1 = Kenneth J. | last2 = Li | first2 = Yong-Xi | last3 = Tan | first3 = Beng-jit | title = Solvated Metal Atom Dispersed Catalysts | journal = Chemistry of Materials | volume = 3 | pages = 30–39 | date = 1991 | issn=0897-4756 | doi = 10.1021/cm00013a013 }} }}{{nano-tech-stub}} 3 : Chemical processes|Nanotechnology|Solutions |
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