| 词条 | Sulfonyl nitrene |
| 释义 |
A sulfonyl nitrene is a chemical compound with generic formula R-SO2N. Known sulfonyl nitrenes include methyl sulfonyl nitrene, trifluoromethyl sulfonyl nitrene, and tolyl sulfonyl nitrene.[1] Also fluorosufoinyl nitrene FSO2N exists, but rearranges to FNSO2.[2] Preparation of sulfonyl nitrenes can be by heating the sulfonyl azide, (RSO2N3.[3] References1. ^{{cite journal|last1=Shainyan|first1=Bagrat A.|last2=Kuzmin|first2=Anton V.|title=Sulfonyl nitrenes from different sources: computational study of formation and transformations|journal=Journal of Physical Organic Chemistry|date=February 2014|volume=27|issue=2|pages=156–162|doi=10.1002/poc.3254}} {{chemistry-stub}}2. ^{{cite journal|last1=Zeng|first1=Xiaoqing|last2=Beckers|first2=Helmut|last3=Willner|first3=Helge|title=Thermally Persistent Fluorosulfonyl Nitrene and Unexpected Formation of the Fluorosulfonyl Radical|journal=Journal of the American Chemical Society|date=4 February 2013|volume=135|issue=6|pages=2096–2099|doi=10.1021/ja312073w}} 3. ^{{cite journal|last1=Abramovitch|first1=Rudolph A.|last2=Knaus|first2=G. N.|last3=Uma|first3=V.|title=Aromatic substitution by sulfonyl nitrenes. Singlet or triplet reactive intermediates|journal=Journal of the American Chemical Society|date=December 1969|volume=91|issue=26|pages=7532–7533|doi=10.1021/ja01054a065}} 1 : Chemical compounds |
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