| 词条 | Terbium(III) nitrate |
| 释义 |
| ImageFile = Terbium nitrate UV comparison.jpg | ImageSize = | ImageAlt = | ImageCaption = Hydrate form of terbium nitrate (left) and luminescence under 254 nm UV light (right) | IUPACName = | OtherNames = Terbium nitrate | Section1 = {{Chembox Identifiers | index3_label = hexahydrate | CASNo = 10043-27-3 | CASNo_Comment = (anhydrous) | CASNo_Ref = {{cascite|correct|CAS}} | CASNo2 = 57584-27-7 | CASNo2_Comment = (pentahydrate) | CASNo2_Ref = {{cascite|correct|CAS}} | CASNo3 = 13451-19-9 | CASNo3_Ref = {{Cascite|correct|CAS}} | PubChem = 24853 | PubChem3 = 202879 | UNII = GVA407Y0IC | StdInChI=1S/3NO3.Tb/c3*2-1(3)4;/q3*-1;+3 | StdInChIKey = YJVUGDIORBKPLC-UHFFFAOYSA-N | SMILES = [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Tb+3] | Section2 = {{Chembox Properties | Formula = Tb(NO3)3 | MolarMass = 344.946 | Appearance = Colorless crystals (hexahydrate)[1] | Density = | MeltingPt = | BoilingPt = | Solubility = | Section3 = {{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}Terbium(III) nitrate is an inorganic chemical compound with the formula Tb(NO3)3. The hexahydrate crystallizes as triclinic colorless crystals with the formula [Tb(NO3)3(H2O)4]·2H2O.[1] It can be used to synthesize materials with green emission.[2] PreparationTerbium(III) nitrate can be prepared by dissolving terbium(III,IV) oxide in a mixture of aqueous HNO3 and H2O2 solution.[3] PropertiesIt reacts with NH4HCO3 to produce Tb2(CO3)3 along with its basic carbonate.[4] It forms Tb(NO3)52- in CH3CN with excess nitrate anions.[5] References1. ^1 {{cite journal|last1=Moret|first1=Emmanuel|last2=Bünzli|first2=Jean-Claude G.|last3=Schenk|first3=Kurt J.|title=Structural and luminescence study of europium and terbium nitrate hexahydrates|journal=Inorganica Chimica Acta|volume=178|issue=1|year=1990|pages=83–88|issn=0020-1693|doi=10.1016/S0020-1693(00)88138-4}} {{Terbium compounds}}{{Nitrates}}2. ^{{cite journal|last1=Xia|first1=Tifeng|last2=Song|first2=Tao|last3=Zhang|first3=Gege|last4=Cui|first4=Yuanjing|last5=Yang|first5=Yu|last6=Wang|first6=Zhiyu|last7=Qian|first7=Guodong|title=A Terbium Metal-Organic Framework for Highly Selective and Sensitive Luminescence Sensing of Hg2+Ions in Aqueous Solution|journal=Chemistry - A European Journal|volume=22|issue=51|year=2016|pages=18429–18434|issn=09476539|doi=10.1002/chem.201603531}} 3. ^{{cite journal|last1=Hou|first1=Zhiyao|last2=Wang|first2=Lili|last3=Lian|first3=Hongzhou|last4=Chai|first4=Ruitao|last5=Zhang|first5=Cuimiao|last6=Cheng|first6=Ziyong|last7=Lin|first7=Jun|title=Preparation and luminescence properties of Ce3+ and/or Tb3+ doped LaPO4 nanofibers and microbelts by electrospinning|journal=Journal of Solid State Chemistry|volume=182|issue=4|year=2009|pages=698–708|issn=0022-4596|doi=10.1016/j.jssc.2008.12.021}} 4. ^{{cite journal|last1=Foger|first1=K.|last2=Hoang|first2=M.|last3=Turney|first3=T. W.|title=Formation and thermal decomposition of rare-earth carbonates|journal=Journal of Materials Science|volume=27|issue=1|year=1992|pages=77–82|issn=0022-2461|doi=10.1007/BF02403646}} 5. ^{{cite journal|last1=Bünzli|first1=Jean-Claude G.|last2=Vuckovic|first2=Milan M.|title=Spectroscopic properties of anhydrous and aqueous solutions of terbium perchlorate and nitrate: Coordination numbers of the Tb(III) ion|journal=Inorganica Chimica Acta|volume=73|year=1983|pages=53–61|issn=00201693|doi=10.1016/S0020-1693(00)90826-0}} 2 : Terbium compounds|Nitrates |
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