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词条 Ammelide
释义

  1. Synthesis

  2. Chemical property

  3. References

{{chembox
| Watchedfields = changed
| verifiedrevid = 444456809
| ImageFile = Ammelide.png
| ImageSize = 150px
| ImageName = Structural formula
| ImageFile1 = Ammelide-3D-balls.png
| ImageName1 = Ball-and-stick model
| IUPACName = 6-Amino-2,4-Dihydroxy-1,3,5-Triazine
| OtherNames = Ammelid, 2-Amino-1,3,5-triazine-4,6-dione, 2-Amino-4,6-dihydroxy-s-triazine
|Section1={{Chembox Identifiers
| Abbreviations =
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 12064
| InChIKey = YSKUZVBSHIWEFK-UHFFFAOYAA
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C3H4N4O2/c4-1-5-2(8)7-3(9)6-1/h(H4,4,5,6,7,8,9)
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = YSKUZVBSHIWEFK-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 645-93-2
| EINECS =
| PubChem = 10927
| SMILES = O=C1NC(=N/C(=O)N1)\
| InChI = 1/C3H4N4O2/c4-1-5-2(8)7-3(9)6-1/h(H4,4,5,6,7,8,9)
| RTECS =
| MeSHName =
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 28134
| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG = C08734
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|Section2={{Chembox Properties
| Formula = C3H4N4O2
| MolarMass = 128.09 g/mol
| Appearance = white powder
| Density =
| MeltingPt =
| MeltingPt_notes =
| BoilingPt =
| BoilingPt_notes =
| Solubility = insoluble
| SolubleOther = soluble in concentrated mineral acids, alkalis and ammonia
| Solvent =
| pKa =
| pKb = }}
|Section7={{Chembox Hazards
| EUClass =
| MainHazards =
| NFPA-H =
| NFPA-F =
| NFPA-R =
| NFPA-S =
| RPhrases =
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| FlashPt =
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| PEL = }}
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Ammelide (6-amino-2,4-dihydroxy-1,3,5-triazine) is a triazine and the hydrolysis product of ammeline.

Synthesis

Ammelide can be obtained by heating dicyandiamide with aqueous ammonia at 160−170 °C. It can also be synthesized by heating melam with concentrated sulfuric acid for a short time at 190 °C.

Chemical property

Ammelide forms salts with both acids (hydrochloric acid, nitric acid, sulfuric acid) and bases (sodium hydroxide, ammonium, calcium hydroxide).

Ammelide decomposes at 170 °C with water to form carbon dioxide and ammonia. It can be converted into cyanuric acid by oxidizing agents (e.g. potassium permanganate) or by boiling with acids or alkalis.

References

  • B. Bann and S.A. Miller, "Melamines and derivatives of melamine", Chemical Reviews, vol.58, p131-172 (1958).

2 : Triazines|Resorcinols

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