| 词条 | Ammonia borane |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 470456677 | ImageFile = Ammonia-borane-from-xtal-3D-balls.png | ImageFile_Ref = {{chemboximage|correct|??}} | ImageSize = 100 | ImageName = Ball and stick model of ammonia borane | IUPACName = Ammoniotrihydroborate{{Citation needed|date=April 2012}} | OtherNames = Borazane{{Citation needed|date=April 2012}} |Section1={{Chembox Identifiers | CASNo = 13774-81-7 | CASNo_Ref = {{cascite|changed|??}} | PubChem = 419330 | ChemSpiderID = 371215 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | SMILES = [BH3-][NH3+] | StdInChI = 1S/BH6N/c1-2/h1-2H3 | StdInChI_Ref = {{stdinchicite|changed|chemspider}} | StdInChIKey = PJYXJGDRFASJSB-UHFFFAOYSA-N | StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} }} |Section2={{Chembox Properties | Formula = {{Chem|BNH|6}} | MolarMass = 30.865 g mol−1 | Appearance = Colorless crystals | Density = 780 mg mL−1 | MeltingPtC = 104 }} |Section3={{Chembox Structure | CrystalStruct = I4mm, tetragonal | Coordination = Tetragonal at B and N | MolShape = Tetrahydral at B and N | Dipole = 5.2 D }} |Section4={{Chembox Hazards | RPhrases = {{R5}} | SPhrases = {{S14}}, {{S15}}, {{S26}}, {{S36/37/39}} }} |Section5={{Chembox Related | OtherCompounds = {{Unbulleted list|Sodium borohydride|Borazine|Borane|Ethane}} }} }} Ammonia borane (also systematically named amminetrihydridoboron), also called borazane, is the chemical compound with the formula H3NBH3. The colourless or white solid is the simplest molecular boron-nitrogen-hydride compound. It has attracted attention as a source of hydrogen fuel, but is otherwise primarily of academic interest. SynthesisReaction of diborane with ammonia mainly gives the diammoniate salt [H2B(NH3)2]+(BH4)−. Ammonia borane is the main product when an adduct of borane is employed in place of diborane:[1] BH3(THF) + NH3 → BH3NH3 + THF Properties and structureThe molecule adopts a structure like ethane, with which it is isoelectronic. The B−N distance is 1.58(2) Å. The B−H and N−H distances are 1.15 and 0.96 Å, respectively. Its similarity to ethane is tenuous since ammonia borane is a solid and ethane is a gas: their melting points differing by 284 °C. This difference is consistent with the highly polar nature of ammonia borane. The H atoms attached to boron are hydridic and those attached to nitrogen are somewhat acidic. The structure of the solid indicates a close association of the NH and the BH centers. The closest H−H distance is 1.990 Å, which can be compared with the H−H bonding distance of 0.74 Å. This interaction is called a dihydrogen bond.[2][3] The original crystallographic analysis of this compound reversed the assignments of B and N. The updated structure was arrived at with improved data using the technique of neutron diffraction that allowed the hydrogen atoms to be located with greater precision. Uses{{main article|Dehydrogenation of amine-boranes}}Ammonia borane has been suggested as a storage medium for hydrogen, e.g. for when the gas is used to fuel motor vehicles. It can be made to release hydrogen on heating, being polymerized first to (NH2BH2)n, then to (NHBH)n,[4] which ultimately decomposes to boron nitride (BN) at temperatures above 1000oC.[5] It is more hydrogen-dense than liquid hydrogen and also able to exist at normal temperatures and pressures.[6] Ammonia borane finds some use in organic synthesis as an air-stable derivative of diborane.[7] Analogous amine-boranesMany analogues have been prepared from primary, secondary, and even tertiary amines:
The first amine adduct of borane was derived from trimethylamine. Borane tert-butylamine complex is prepared by the reaction of sodium borohydride with t-butylammonium chloride. Generally adduct are more robust with more basic amines. Variations are also possible for the boron component, although primary and secondary boranes are less common.[8] Additionally, many complexes of borane have been prepared, including borane dimethylsulfide (Me2S→BH3) and borane–tetrahydrofuran (THF→BH3). References1. ^{{ cite journal |author1=Shore, S. G. |author2=Boddeker, K. W. | title = Large Scale Synthesis of H2B(NH3)2+BH4− and H3NBH3 | journal = Inorganic Chemistry | year = 1964 | volume = 3 | issue = 6 | pages = 914–915 | doi = 10.1021/ic50016a038 }} {{Boron compounds}}2. ^1 {{ cite journal | last = Klooster | first = W. T. |author2= Koetzle, T. F.|author3= Siegbahn, P. E. M.|author4= Richardson, T. B.|author5= Crabtree, R. H. | title = Study of the N−H···H−B Dihydrogen Bond Including the Crystal Structure of BH3NH3 by Neutron Diffraction | journal = Journal of the American Chemical Society | year = 1999 | volume = 121 | issue = 27 | pages = 6337–6343 | doi = 10.1021/ja9825332 }} 3. ^{{ cite book | last = Boese | first = R. |author2= Niederprüm, N.|author3= Bläser, D. | title = Molecules in Natural Science and Medicine | editor = Maksic, Z. B. |editor2=Eckert-Masic, M. | publisher = Ellis Horwood | location = Chichester, England | year = 1992 | isbn = 978-0135615980 }} 4. ^{{ cite journal |author1=Gutowski, M. |author2=Autrey, T. | title = Features: Hydrogen gets onboard | journal = Chemistry World | year = 2006 | volume = 3 | issue = 3 | url = http://www.rsc.org/chemistryworld/Issues/2006/March/HydrogenOnBoard.asp }} 5. ^{{ cite journal |author1=Frueh, S. |author2=Kellett, R. |author3=Mallery, C. |author4=Molter |author5=T. |author6=Willis, W. S. |author7=King'ondu, C. |author8=Suib, S. L. | title = Pyrolytic Decomposition of Ammonia Borane to Boron Nitride | journal = Inorganic Chemistry | year = 2011 | volume = 50 | issue = 3 | pages = 783–792 | doi = 10.1021/ic101020k }} 6. ^{{ cite journal |author1=Stephens, F. H. |author2=Pons, V. |author3=Baker, R. T. | title = Ammonia–Borane: The Hydrogen Source par excellence? | journal = Dalton Transactions | year = 2007 | volume = 2007 | issue = 25 | pages = 2613–2626 | doi = 10.1039/b703053c }} 7. ^{{ cite encyclopedia | last = Andrews | first = G. C. | title = Borane–Ammonia | encyclopedia = Encyclopedia of Reagents for Organic Synthesis | editor-first = L. | editor-last = Paquette | year = 2004 | publisher = John Wiley & Sons | location = New York | doi = 10.1002/047084289 }} 8. ^Staubitz, A.; Robertson, A. P. M.; Manners, I., "Ammonia-Borane and Related Compounds as Dihydrogen Sources", Chemical Reviews 2010, volume 110, 4079-4124.. {{DOI|10.1021/cr100088b}} 3 : Inorganic compounds|Boranes|Inorganic amines |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。