| 词条 | Thulium(III) bromide |
| 释义 |
| Reference = | Name =Thulium(III) bromide | IUPACName =Tribromothulium | PIN = | SystematicName = | OtherNames = | ImageFile = | ImageSize = | ImageAlt = | ImageName = | Section1 = {{Chembox Identifiers | 3DMet = | Abbreviations = | Beilstein = | CASNo = 14456-51-0 | CASNo_Comment = | ChEBI = | ChemSpiderID = | EINECS = | EC_number = 238-444-4 | EC_number_Comment = | Gmelin = | InChI = InChI=1S/3BrH.Tm/h3*1H;/q;;;+3/p-3 | InChIKey= HQSWGSFQSCMHFQ-UHFFFAOYSA-K | KEGG = | MeSHName = | PubChem = 84454 | RTECS = | SMILES = [Tm+3].[Br-].[Br-].[Br-] | UNNumber = | Section2 = {{Chembox Properties | AtmosphericOHRateConstant = | Appearance = White crystalline solid | BoilingPtC = 1440 | BoilingPt_ref = [1] | BoilingPt_notes = | Density = | Formula = TmBr3 | HenryConstant = | LogP = | MolarMass = 408.65[1] | MeltingPtC = 952 | MeltingPt_ref = [1] | MeltingPt_notes = | pKa = | pKb = | Solubility = Soluble[4] | SolubleOther = | Solvent = | VaporPressure = | Section3 = {{Chembox Structure | Coordination = | CrystalStruct = | MolShape = | Section4 = {{Chembox Thermochemistry | DeltaGf = | DeltaHc = | DeltaHf = | Entropy = | HeatCapacity = | Section5 = {{Chembox Explosive | ShockSens = | FrictionSens = | DetonationV = | REFactor = | Section7 = {{Chembox Hazards | AutoignitionPt = | ExploLimits = | ExternalSDS = | FlashPt = | LD50 = | LC50 = | MainHazards = | NFPA-F = 0 | NFPA-H = 2 | NFPA-R = 0 | NFPA-S = | PEL = | REL = | GHSPictograms = {{GHS exclamation mark}} | GHSSignalWord = Warning | HPhrases ={{H-phrases|315|319|335}}[1] | PPhrases ={{P-phrases|261|305+351+338}}[1] {{P-phrases|264|271|280|302+352|304+340|312|321|332+313|337+313|362|403+233|405|501}}[2] | Section9 = {{Chembox Related | OtherAnions = | OtherCations = | OtherFunction = | OtherFunction_label = | OtherCompounds = }}Thulium(III) bromide is a crystalline compound of one thulium atom and three bromine atoms.[3] It is a white powder at room temperature.[4] It is hygroscopic.[5] UsageThulium(III) bromide is used as a reagent for the complexation of lanthanide bromides with aluminium bromide, and as a reactant for preparing alkali metal thulium bromides.[6] It is also used to create discharge lamps that are free of mercury.[7] References1. ^1 {{cite web|title=Thulium(III) bromide anhydrous, powder, 99.99% {{!}} Sigma-Aldrich|url=http://www.sigmaaldrich.com/catalog/product/aldrich/439630?lang=en®ion=US|website=www.sigmaaldrich.com|accessdate=21 December 2016}} {{Thulium compounds}}2. ^{{cite web|title=Thulium bromide {{!}} Br3Tm - PubChem|url=https://pubchem.ncbi.nlm.nih.gov/compound/Thulium_bromide#datasheet=lcss§ion=GHS-Classification|website=pubchem.ncbi.nlm.nih.gov|accessdate=21 December 2016}} 3. ^{{cite book|last1=Phillips|first1=Sidney L.|last2=Perry|first2=Dale L.|title=Handbook of inorganic compounds|date=1995|publisher=CRC Press|location=Boca Raton|isbn=9780849386718|page=415}} 4. ^1 2 3 {{cite web|last1=Elements|first1=American|title=Thulium Bromide|url=https://www.americanelements.com/thulium-bromide-14456-51-0|website=American Elements|accessdate=21 December 2016}} 5. ^{{cite web|title=THULIUM BROMIDE {{!}} 14456-51-0|url=http://www.chemicalbook.com/ChemicalProductProperty_EN_CB0434861.htm|website=www.chemicalbook.com|accessdate=21 December 2016}} 6. ^1 {{cite web|title=14456-51-0 - Thulium(III) bromide, ultra dry, 99.99% (REO) - 47196 - Alfa Aesar|url=https://www.alfa.com/en/catalog/047196/|website=www.alfa.com|accessdate=21 December 2016}} 7. ^{{cite web|last1=Kashiwagi|first1=Takahito|last2=Ishida|first2=Masazumi|last3=Matsuda|first3=Mikio|last4=Uemura|first4=Kozo|title=Mercury-free high-pressure discharge lamp and luminaire using the same|url=http://www.google.ch/patents/US20070138964|accessdate=21 December 2016|date=2007}} 2 : Bromides|Thulium compounds |
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