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词条 Trans,cis-2,6-Nonadienal
释义

  1. Biosynthesis

  2. See also

  3. References

{{DISPLAYTITLE:trans,cis-2,6-Nonadienal}}{{Chembox
| Name = trans,cis-2,6-Nonadienal
| ImageFile = Trans-2,cis-6-Nonadienal.png
| ImageSize =
| ImageAlt =
| IUPACName = (E,Z)-Nona-2,6-dienal
| OtherNames = (E,Z)-2,6-Nonadienal
Violet leaf aldehyde
Cucumber aldehyde
|Section1={{Chembox Identifiers
| CASNo = 557-48-2
| PubChem = 643731
| UNII = 93E895X03C
| ChEBI = 7610
| ChemSpiderID = 558840
| InChI=1S/C9H14O/c1-2-3-4-5-6-7-8-9-10/h3-4,7-9H,2,5-6H2,1H3/b4-3-,8-7+
| InChIKey = HZYHMHHBBBSGHB-ODYTWBPASA-N
| SMILES = CC/C=C\\CC/C=C/C=O }}
|Section2={{Chembox Properties
| C=9|H=14|O=1
| MolarMass =
| Appearance = Colorless oil
| Density =
| MeltingPt =
| BoilingPt =
| Solubility = }}
|Section3={{Chembox Hazards
| GHSPictograms = {{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|315|317}}
| PPhrases = {{P-phrases|261|264|272|280|302+352|321|332+313|333+313|362|363|501}}
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
}}

trans,cis-2,6-Nonadienal is an organic compound that is classified as a doubly unsaturated derivative of nonanal. The molecule consists of a α,β-unsaturated aldehyde with an isolated alkene group. The compound has attracted attention as the essence of cucumbers,[1][2] but it is also found in bread crust[3] and freshly cut watermelon.

Biosynthesis

Isotopic labeling has indicated that nonadienal is formed from alpha-linolenic acid.[4] Such reactions are typically catalyzed by hydroperoxide lyases.

See also

  • 2-Nonenal - another potent odorant in cucumber

References

1. ^{{cite journal|title=Unsaturated aliphatic C9-aldehydes as natural flavorants: (E,Z)-2,6-nonadienal|authors=Kula, Jozef; Sadowska, Halina|journal=Perfumer & Flavorist|year=1993|volume=18|pages=23–5}}
2. ^{{cite journal|last1=Schieberle |first1=P.|last2=Ofner |first2=S.|last3=Grosch |first3=W.|title=Evaluation of Potent Odorants in Cucumbers (Cucumis sativus) and Muskmelons (Cucumis melo) by Aroma Extract Dilution Analysis|journal=Journal of Food Science|date=January 1990|volume=55|issue=1|pages=193–195|doi=10.1111/j.1365-2621.1990.tb06050.x}}
3. ^{{cite journal|title=Chemistry of Bread Aroma: A Review|authors=Cho, In Hee; Peterson, Devin G.|journal=Food Science and Biotechnology|year=2010|volume=19|pages=575–582|doi=10.1007/s10068-013-0240-4}}
4. ^{{cite journal|last1=Grosch|first1=Werner|last2=Schwarz|first2=Jorg M.|title=Linoleic and linolenic acid as precursors of the cucumber flavor|journal=Lipids|date=May 1971|volume=6|issue=5|pages=351–352|doi=10.1007/BF02531828}}
{{DEFAULTSORT:Nonadienal, trans,cis-2,6-}}

2 : Fatty aldehydes|Flavors

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