| 词条 | Trifluoronitrosomethane |
| 释义 |
| Name = Trifluoronitrosomethane | ImageFile =TFNM.svg | ImageSize = 160px | ImageName = Trifluoronitrosomethane | ImageFile1 =Trifluoronitrosomethane-3D-spacefill.png | ImageSize1 = 160px | ImageName1 = Trifluoronitrosomethane | IUPACName = Trifluoronitrosomethane | OtherNames = Trifluoro-nitrosomethane Trifluoro-nitroso-methane Nitrosotrifluoromethane |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 60949 | PubChem = 67630 | InChI = 1S/CF3NO/c2-1(3,4)5-6 | InChIKey = PGOMVYSURVZIIW-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 334-99-6 }} |Section2={{Chembox Properties | C=1 | F=3 | N=1 | O=1 | Appearance = Deep blue gas | Odor = | MeltingPtC = -196.6 | BoilingPtC = -85 | Density = | Solubility = |Section3= |Section7={{Chembox Hazards | ExternalSDS = | MainHazards = toxic | NFPA-H = 3 | NFPA-F = 1 | NFPA-R = 0 | FlashPt = | RPhrases = | SPhrases = | PEL = | IDLH = | REL = | LC50 = }} Trifluoronitrosomethane (commonly abbreviated TFNM) is a toxic halomethane. Its distinctive deep blue colour is unusual for a gas. HistoryTrifluoronitrosomethane was synthesized for the first time in 1936 by Otto Ruff and Manfred Giese at the University of Wrocław.[1] It was created through the fluorination of silver cyanide in the presence of silver nitrate and silver oxide. ProductionTrifluoronitrosomethane can be produced from the reaction of trifluoroiodomethane and nitric oxide under a UV light with a yield of up to 90% in normal pressure. A small amount of mercury is needed as catalyst. The reaction results in the creation of iodine as a by-product.[2][3][4] PropertiesTrifluoronitrosoethylene is also a deep blue gas.[5] Although it is somewhat more kinetically stable due to its fluorine substituents, trifluoronitrosomethane, like other nitroso compounds, has a weak C–N bond of only 39.9 kcal/mol.[6] References1. ^O. Ruff und M. Giese: Das Trifluor-nitroso-methan, CF3NO (III.) In: Ber dtsch Chem Ges 69, 1936, S. 684–689. {{DOI|10.1002/cber.19360690411}} 2. ^A. Senning: N-, 0-, AND S-trihalomethyl compounds. In: Chemical Reviews 65, 1964, S. 385–412. 3. ^C. W. Taylor u. a.: The Preparation of Polyfluoronitrosoalkanes from Nitrosyl Polyfluoroacylates. In: The Journal of organic chemistry 27, 1962, S. 1064–1066. {{DOI|10.1021/jo01050a523}} 4. ^J. D. Park u. a.: Preparation of Perfluoronitrosoalkanes. Reaction of Trifluoroacetic Anhydride with Nitrosyl Chloride. In: The Journal of organic chemistry 27, 1962, S. 1642. {{DOI|10.1021/jo01051a519}} 5. ^{{cite journal |last1=Griffin |first1=C. E. |last2=Haszeldine |first2=R. N. |title=279. Perfluoroalkyl derivatives of nitrogen. Part VIII. Trifluoronitrosoethylene and its polymers |journal=Journal of the Chemical Society (Resumed) |date=1960 |pages=1398 |doi=10.1039/JR9600001398}} 6. ^{{Cite book|title=Comprehensive Handbook of Chemical Bond Energies|last=Luo|first=Yu-Ran|publisher=CRC Press|year=2007|isbn=0-8493-7366-2|location=Boca Raton, Fl.|pages=406}} External links
3 : Trifluoromethyl compounds|Nitroso compounds|Gases with color |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。