| 词条 | Trimethylplatinum iodide |
| 释义 |
| ImageFile = FUBREA.png | ImageSize = | ImageAlt = | IUPACName = | OtherNames = Iodotrimethylplatinum(IV) |Section1={{Chembox Identifiers | CASNo = 14364-93-3 | PubChem = 11824720 | ChemSpiderID = 11522740 | SMILES = }} |Section2={{Chembox Properties | C=12|H=36|Pt=4|I=4 | MolarMass = | Appearance = white solid | Density = | MeltingPt = 190-195 °C | MeltingPt_notes = | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | GHSPictograms = {{GHS02}}{{GHS07}} | GHSSignalWord = Warning | HPhrases = {{H-phrases|228|302|312|315|319|332|413}} | PPhrases = {{P-phrases|210|240|241|261|264|270|271|273|280|301+312|302+352|304+312|304+340|305+351+338|312|321|322|330|332+313|337+313|362|363|370+378|501}} | MainHazards = | FlashPt = | AutoignitionPt = }} }}Trimethylplatinum iodide is the organoplatinum complex with the formula [(CH3)3PtI]4. It is a white, air-stable solid that was one of the first organometallic complexes reported. It arises from the reaction of potassium hexachloroplatinate with methylmagnesium iodide.[1] The complex consists of four octahedral Pt(IV) centers, which share iodide as triply bridging ligands.[2] The complex undergoes diverse reactions involving cleaving Pt-I bridges. Derived complexes include (CH3)3PtI(bipy) and (CH3)3PtI(NH3)2. Replacement of the iodide with hydroxide gives [(CH3)3PtOH]4. References1. ^{{cite journal|authors=Baldwin, J. C.; Kaska, W. C.|title=Improved Isolation Procedure for the Preparation of Iodo(trimethyl)platinum(IV)|journal=Inorg. Chem.|year=1975|volume=14|pages=2020|doi=10.1021/ic50150a063}} 2. ^{{cite journal|authors=Ebert, K. H.; Massa, W.; Donath, H.; Lorberth, J.; Seo, B. S.; Herdtweck, E.|title=Organoplatinum Compounds: VI. Trimethylplatinum Thiomethylate and Trimethylplatinum Iodide. The Crystal Structures of [(CH3)3PtS(CH3)]4 and [(CH3)3PtI]4·0.5CH3I|journal=J. Organomet. Chem.|year=1998|volume=559|pages=203-207|doi=10.1016/S0022-328X(98)00414-8}} 2 : Organoplatinum compounds|Iodides |
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