词条 | Anthrone |
释义 |
| Watchedfields = changed | verifiedrevid = 443392881 | ImageFile_Ref = {{chemboximage|correct|??}} | ImageFile = Anthrone.png | ImageSize = 180 | ImageName = Skeletal formula | ImageFile1 = Anthrone-3D-balls.png | ImageSize1 = 210 | ImageName1 = Ball-and-stick model | IUPACName = 10H-Anthracen-9-one | OtherNames = Carbothrone; anthranone; 9-oxoanthracene |Section1={{Chembox Identifiers | InChIKey = RJGDLRCDCYRQOQ-UHFFFAOYAA | ChEMBL_Ref = {{ebicite|correct|EBI}} | ChEMBL = 124440 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = RJGDLRCDCYRQOQ-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 90-44-8 | PubChem = 7018 | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = 33835 | SMILES = O=C2c1c(cccc1)Cc3c2cccc3 | InChI = 1/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID =6751 |Section2={{Chembox Properties | C =14|H=10|O=1 | Appearance = White to light yellow needles | Density = Solid | MeltingPtC = 155 to 158 | MeltingPt_notes = | BoilingPtC = 721 | BoilingPt_notes = | Solubility = Insoluble |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}Anthrone is a tricyclic aromatic ketone. It is used for a popular cellulose assay and in the colorometric determination of carbohydrates.[1] The anthrones are used in pharmacy as laxative. They stimulate the motion of the colon and are reduce water reabsorption. Anthrones can be extracted from a number of plant species, including Rhamnus frangula, Aloe ferox, Rheum officinale and Cassia senna.{{cn|date=November 2017}} SynthesisAnthrone can be prepared from anthraquinone by reduction with tin, glacial acetic acid and hydrochloric acid, or cyclization of o-benzylbenzoic acid with liquid Hydrogen fluoride.
References1. ^{{cite journal | title = Determination of Yeast Carbohydrates with the Anthrone Reagent | journal = Nature | volume = 170 | pages = 626–627 | year = 1952 | doi = 10.1038/170626a0 | author = Trevelyan, W. E. | pmid = 13002392 | last2 = Forrest | first2 = RS | last3 = Harrison | first3 = JS | issue = 4328}} {{ketone-stub}}2. ^{{cite journal|title=ANTHRONE|journal=Organic Syntheses|date=1928|volume=8|pages=8|doi=10.15227/orgsyn.008.0008}} 3. ^{{cite journal|last1=Fieser|first1=Louis F.|last2=Hershberg|first2=E. B.|title=Inter- and Intramolecular Acylations with Hydrogen Fluoride|journal=Journal of the American Chemical Society|date=May 1939|volume=61|issue=5|pages=1272–1281|doi=10.1021/ja01874a079}} 2 : Aromatic ketones|Anthracenes |
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