“Bisphenol”的意思、由来-开放百科全书

The bisphenols ({{IPAc-en|ˈ|b|ɪ|s|f|ᵻ|n|ɒ|l}}) are a group of chemical compounds with two hydroxyphenyl functionalities. Most of them are based on diphenylmethane. The exceptions are bisphenol S, P, and M. "Bisphenol" is a common name; the letter following refers to one of the reactants. Bisphenol A is the most popular representative of this group, often simply called "bisphenol."^[1]

List

Structural formula

Name

CAS

Reactants

Systematic name

Bisphenol A

80-05-7

Phenol

Acetone

2,2-Bis(4-hydroxyphenyl)propane

Bisphenol AP

1571-75-1

Phenol

Acetophenone

1,1-Bis(4-hydroxyphenyl)-1-phenyl-ethane

Bisphenol AF

1478-61-1

Phenol

Hexafluoroacetone

2,2-Bis(4-hydroxyphenyl)hexafluoropropane

Bisphenol B

77-40-7

Phenol

Butanone

2,2-Bis(4-hydroxyphenyl)butane

Bisphenol BP

1844-01-5

Phenol

Benzophenone

Bis-(4-hydroxyphenyl)diphenylmethane

Bisphenol C

79-97-0

o-cresol

Acetone

2,2-Bis(3-methyl-4-hydroxyphenyl)propane

Bisphenol C 2

14868-03-2

Phenol

Dichloromethane

Bis(4-hydroxyphenyl)-2,2-dichlorethylene

Bisphenol E

2081-08-5

Phenol

Acetaldehyde

1,1-Bis(4-hydroxyphenyl)ethane

Bisphenol F

620-92-8

Phenol

Formaldehyde

Bis(4-hydroxyphenyl)methane

Bisphenol G

127-54-8

2-Isopropylphenol

Acetone

2,2-Bis(4-hydroxy-3-isopropyl-phenyl)propane

Bisphenol M

13595-25-0

1,3-Bis(2-(4-hydroxyphenyl)-2-propyl)benzene

Bisphenol S

80-09-1

Phenol

Sulfur trioxide

Bis(4-hydroxyphenyl)sulfone

Bisphenol P

2167-51-3

1,4-Bis(2-(4-hydroxyphenyl)-2-propyl)benzene

Bisphenol PH

24038-68-4

2-Phenylphenol

Acetone

5,5’ -(1-Methylethyliden)-bis[1,1’-(bisphenyl)-2-ol]propane

Bisphenol TMC

129188-99-4

Phenol

3,3,5-Trimethylcyclohexanone

1,1-Bis(4-hydroyphenyl)-3,3,5-trimethyl-cyclohexane

Bisphenol Z

843-55-0

Phenol

Cyclohexanone

1,1-Bis(4-hydroxyphenyl)-cyclohexane

Dinitrobisphenol A

5329-21-5

Bisphenol A

nitric acid

2,2-Bis(4-hydroxy-3-nitrophenyl)propane

Tetrabromobisphenol A

79-94-7

Bisphenol A

bromine

2,2-Bis(4-hydroxy-3,5-dibromophenyl)propane

Health effects

Bisphenols A (BPA) and S (BPS) have been shown to be endocrine disruptors.^[2]^[3] Due to its high production volumes, BPA has been characterised as a "pseudo-persistent" chemical,^[4] leading to its spreading and potential accumulation in a variety of environmental matrices, even though it has a fairly short half-life.^[5]

References

1. ^{{cite encyclopedia|authors=Helmut Fiege, Heinz-Werner Voges, Toshikazu Hamamoto, Sumio Umemura, Tadao Iwata, Hisaya Miki, Yasuhiro Fujita, Hans-Josef Buysch, Dorothea Garbe, Wilfried Paulus |encyclopedia=Ullmann's Encyclopedia of Industrial Chemistry|year=2002|publisher=Wiley-VCH|location=Weinheim|doi=10.1002/14356007.a19_313|isbn=978-3527306732 |chapter=Phenol Derivatives }}.
2. ^{{cite web|title=BPA-Free Plastic Containers May Be Just as Hazardous|url=http://www.scientificamerican.com/article/bpa-free-plastic-containers-may-be-just-as-hazardous/|website=Scientific American|accessdate=8 August 2015}}
3. ^{{cite web|title=Bisphenol A (BPA) & Bisphenol S (BPS)|url=http://saferchemicals.org/chemicals/bpa-bps/|website=SaferChemicals.org|accessdate=8 August 2015}}
4. ^{{Cite journal|title = Bisphenol A and its structural analogues in household waste paper|url = http://www.sciencedirect.com/science/article/pii/S0956053X15300349|journal = Waste Management|date = 2015-10-01|pages = 39–47|volume = 44|doi = 10.1016/j.wasman.2015.07.017|first = K.|last = Pivnenko|first2 = G. A.|last2 = Pedersen|first3 = E.|last3 = Eriksson|first4 = T. F.|last4 = Astrup|pmid=26194879}}
5. ^See Bisphenol A#Environmental effects for extensive discussion