| 释义 |
- References
- External links
{{More footnotes|date=June 2012}}{{Chembox
| Watchedfields = changed
| verifiedrevid = 427089245
| ImageFile = Bromoiodomethane.png
| ImageFile_Ref = {{chemboximage|correct|??}}
| ImageSize = 100
| ImageName = Stereo, skeletal formula of bromoiodomethane
| ImageFile1 = Bromoiodomethane-3D-vdW.png
| ImageFile1_Ref = {{chemboximage|correct|??}}
| ImageSize1 = 100
| ImageName1 = Spacefill model of bromoiodomethane
| PIN = Bromo(iodo)methane
| OtherNames = {{Unbulleted list|Bromoiodomethane|Bromomethyl iodide{{Citation needed|date=June 2012}}|Iodobromomethane{{Citation needed|date=June 2012}}
}}
|Section1={{Chembox Identifiers
| CASNo = 557-68-6
| CASNo_Ref = {{cascite|correct|??}}
| PubChem = 68407
| ChemSpiderID = 61690
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| SMILES = BrCI
| StdInChI = 1S/CH2BrI/c2-1-3/h1H2
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = TUDWMIUPYRKEFN-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
}}
|Section2={{Chembox Properties
| C = 1
| H = 2
| Br = 1
| I = 1
| Appearance = Colourless liquid
| Density = 2.93 g mL−1
| MeltingPtK = 274
| BoilingPtC = 138 to 141
| RefractIndex = 1.6382
}}
|Section3={{Chembox Hazards
| GHSPictograms = {{GHS corrosion}} {{GHS exclamation mark}}
| GHSSignalWord = DANGER
| HPhrases = {{H-phrases|315|318|335}}
| PPhrases = {{P-phrases|261|280|305+351+338}}
}}
|Section4={{Chembox Related
| OtherFunction_label = alkanes
| OtherFunction = {{Unbulleted list|Bromomethane|Bromoethane}}
}}
}}Bromoiodomethane is a liquid mixed halomethane very soluble in chloroform. Its critical point is at 367.85 °C and 6.3 MPa and refractive index is 1.6382 (20 °C, D). References- {{cite journal |author1=Tarnovsky A. N. |author2=Wall M. |author3=Gustafsson M. |author4=Lascoux N. |author5=Sundström V. |author6=Åkesson E. | date = March 2002 | title = Ultrafast Study of the Photodissociation of Bromoiodomethane in Acetonitrile upon 266 nm Excitation | journal = J. Phys. Chem. A | volume = 106 | issue = 25 | pages = 5999–6005(7) | pmid = | doi = 10.1021/jp014306j | url = http://pubs.acs.org/cgi-bin/abstract.cgi/jpcafh/2002/106/i25/abs/jp014306j.html | accessdate = 2007-06-29 |bibcode=2002JPCA..106.5999T }}
- {{cite journal |author1=Liu Y.-J. |author2=Ajitha D. |author3=Krogh J. W. |author4=Tarnovsky A. N. |author5=Lindh R. | date = December 2005 | title = Spin-Orbit Ab Initio Investigation of the Photolysis of Bromoiodomethane | journal = ChemPhysChem | volume = 7 | issue = 4 | pages = 955–963(9) | pmid = 16596616 | doi = 10.1002/cphc.200500654 | url = http://www3.interscience.wiley.com/cgi-bin/abstract/112580100/ABSTRACT?CRETRY=1&SRETRY=0 | accessdate = 2007-06-29 }}{{dead link|date=February 2019|bot=medic}}{{cbignore|bot=medic}}
- {{cite journal |author1=Zheng, X. |author2=Phillips, D. L. | date = August 2000 | title = Photoisomerization reaction of CH2BrI following A-band and B-band photoexcitation in the solution phase: Transient resonance Raman observation of the iso-CH2I-Br photoproduct | journal = J. Chem. Phys. | volume = 113 | issue = 8 | pages = 3194–3203(10) | pmid = | doi = 10.1063/1.1286920 | bibcode = 2000JChPh.113.3194Z }}
- {{cite journal |author1=Liu K. |author2=Zhao H. |author3=Wang C. |author4=Zhang A. |author5=Ma S. |author6=Li Z. | date = January 2005 | title = A theoretical study of bond selective photochemistry in CH2BrI | journal = J. Chem. Phys. | volume = 122 | issue = 4| pages = 044310| pmid = 15740251| doi = 10.1063/1.1835955 | url = http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JCPSA6000122000004044310000001&idtype=cvips&gifs=yes | accessdate = 2007-06-29 |bibcode = 2005JChPh.122d4310L }}
External links- [https://web.archive.org/web/20110519070246/http://www.atmosphere.mpg.de/enid/0%2Caa609a5350454b5452554d5f7375626b6174092d09496f646f616c6b616e6573253238432532434825324346253243436c253243427225324349253239093a095350454b5452554d5f6b6174092d0948616c6f67656e6f2d616c6b616e65732532432b2d616c6b796c2b7261646963616c73093a095350454b5452554d5f73746f66666e616d65092d0962726f6d6f696f646f6d657468616e65093a095f7472636964092d093531363935/Spectra/Catalogue_5p4.html UV Spectra data]
{{Halomethanes}}{{Organohalide-stub}} 3 : Halomethanes|Organobromides|Organoiodides |