词条 | Compressibility equation |
释义 |
In statistical mechanics and thermodynamics the compressibility equation refers to an equation which relates the isothermal compressibility (and indirectly the pressure) to the structure of the liquid. It reads: where is the number density, g(r) is the radial distribution function and is the isothermal compressibility. Using the Fourier representation of the Ornstein-Zernike equation the compressibility equation can be rewritten in the form: where h(r) and c(r) are the indirect and direct correlation functions respectively. The compressibility equation is one of the many integral equations in statistical mechanics. References
2 : Statistical mechanics|Thermodynamic equations |
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