| 词条 | Di-tert-butylzinc |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 446485380 | Name = Di-tert-butylzinc | ImageFile = Di-tert-butylzinc.png | ImageSize =150px | ImageFile1 = Di-tert-butylzinc-from-xtal-3D-balls-B.png | ImageSize1 =170px | IUPACName = Bis(dimethylethyl)zinc | OtherNames = Di-tert-butylzinc |Section1={{Chembox Identifiers | CASNo = 16636-96-7 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 545313 | ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} | ChemSpiderID = 10750751 | SMILES = CC(C)(C)[Zn]C(C)(C)C | InChI = 1/2C4H9.Zn/c2*1-4(2)3;/h2*1-3H3;/rC8H18Zn/c1-7(2,3)9-8(4,5)6/h1-6H3 | InChIKey = KYHHMFUFEIHUHB-UUODNYSZAB | StdInChI_Ref = {{stdinchicite|changed|chemspider}} | StdInChI = 1S/2C4H9.Zn/c2*1-4(2)3;/h2*1-3H3; | StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} | StdInChIKey = KYHHMFUFEIHUHB-UHFFFAOYSA-N }} |Section2={{Chembox Properties | C=8 | H=18 | Zn=1 | Appearance = | Density = | MeltingPt = | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }}Di-tert-butylzinc is a compound with the formula ZnC8H18. This compound is used as a meta activating reagent in the syntheses of N,N-dimethyl-3-iodoaniline from N,N-dimethylaniline.[1] References1. ^{{cite journal | doi = 10.1002/anie.200600720 | title = Directedmeta-Metalation Using Alkali-Metal-Mediated Zincation | year = 2006 | last1 = Armstrong | first1 = David R. | last2 = Clegg | first2 = William | last3 = Dale | first3 = Sophie H. | last4 = Hevia | first4 = Eva | last5 = Hogg | first5 = Lorna M. | last6 = Honeyman | first6 = Gordon W. | last7 = Mulvey | first7 = Robert E. | journal = Angewandte Chemie International Edition | volume = 45 | issue = 23 | pages = 3775}} {{Zinc compounds}}{{DEFAULTSORT:Di-Tert-Butylzinc}}{{Organic-compound-stub}} 2 : Organozinc compounds|Tert-butyl compounds |
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