| 词条 | Lithium amide |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 470454395 | ImageFile1 = File:Lithium_azanide.png | ImageSize1 = 130px | ImageFile2 = File:Unit cell of LiNH2.png | ImageCaption2 = __ Li+ __ N3− __ H+ | IUPACName = Lithium amide | OtherNames = Lithamide |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 22939 | InChI = 1/Li.H2N/h;1H2/q+1;-1 | InChIKey = AFRJJFRNGGLMDW-UHFFFAOYAO | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Li.H2N/h;1H2/q+1;-1 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = AFRJJFRNGGLMDW-UHFFFAOYSA-N | CASNo_Ref = {{cascite|changed|??}} | CASNo = 7782-89-0 | PubChem = 24532 | SMILES = [Li+].[NH2-] }} |Section2={{Chembox Properties | Formula = {{chem|Li|N|H|2}} | MolarMass = 22.96 g/mol | Appearance = white solid | Density = 1.178 g/cm3 | MeltingPtC = 375 | BoilingPtC = 430 | BoilingPt_notes = decomposes | Solubility = reacts | SolubleOther = slightly soluble in ethanol insoluble in ammonia |Section4={{Chembox Thermochemistry | DeltaHf = -182 kJ/mol |Section7={{Chembox Hazards | MainHazards = | NFPA-H = 3 | NFPA-F = 1 | NFPA-R = 2 | NFPA-S = W | FlashPt = | AutoignitionPt = }} Lithium amide is an inorganic compound with the chemical formula Li+NH2−, i.e. it is composed of a lithium cation, and the conjugate base of ammonia. It is a white solid with a tetragonal crystal structure. Lithium amidesThe anionic conjugate bases of amines are known as amides. Thus a lithium amide may also refer to any compound in the class of the lithium salt of an amine. These chemicals have the general form Li+NR2−, with the chemical lithium amide itself as the parent structure. Common lithium amides include lithium diisopropylamide (LDA), lithium tetramethylpiperidide (LiTMP), and lithium hexamethyldisilazide (LiHMDS). Lithium amide can be made by adding lithium metal to liquid ammonia: 2Li + 2NH3 → 2LiNH2 + H2 Lithium amides in general can be similarly formed, substituting ammonia with the appropriate amine: 2Li + 2R2NH → 2LiNR2 + H2 Lithium amides are very reactive compounds and can act as strong bases. Unless the nitrogen atom is hindered, they can also act as nucleophiles. ExamplesLithium tetramethylpiperidide has been crystallised as a tetramer.[1] On the other hand, the lithium derivative of bis(1-phenylethyl)amine crystallises as a trimer:[2] It is also possible to make mixed oligomers of metal alkoxides and amides.[3] These are related to the superbases which are mixtures of metal alkoxides and alkyls. The cyclic oligomers form when the nitrogen of the amide forms a sigma bond to a lithium while the nitrogen lone pair binds to another metal centre. Other organolithium compounds (such as BuLi) are generally considered to exist in and function via high-order, aggregated species. See also
References1. ^{{cite journal |author1=M.F. Lappert |author2=M.J. Slade |author3=A. Singh |author4=J.L. Atwood |author5=R.D. Rogers |author6=R. Shakir | journal=Journal of the American Chemical Society | year= 1983 | volume=105 | issue=2 | pages=302–304 | title= Structure and reactivity of sterically hindered lithium amides and their diethyl etherates: crystal and molecular structures of [Li{N(SiMe3)2}(OEt2)]2 and tetrakis(2,2,6,6-tetramethylpiperidinatolithium) | doi=10.1021/ja00340a031}} * Merck Index, 11th Edition, 5398.2. ^{{cite journal |author1= D.R. Armstrong |author2= K.W. Henderson |author3= A.R. Kennedy |author4= W.J. Kerr |author5= F.S. Mair |author6= J.H. Moir |author7= P.H. Moran |author8= R. Snaith |journal= Dalton Transactions |year= 1999 |pages= 4063–4068 |title= Structural studies of the chiral lithium amides [{PhC(H)Me}2NLi] and [PhCH2{PhC(H)Me}NLi·THF] derived from α-methylbenzylamine |doi= 10.1039/A904725E }} 3. ^{{cite journal |author1=K.W. Henderson, D.S. Walther |author2=P.G. Williard |lastauthoramp=yes| journal=Journal of the American Chemical Society | year= 1995 | volume=117 | issue=33 | pages= 8680–8681 | title=Identification of a Unimetal Complex of Bases by 6Li NMR Spectroscopy and Single-Crystal Analysis | doi=10.1021/ja00138a030 }} External links{{Lithium compounds}} 2 : Lithium compounds|Metal amides |
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