| 词条 | Mercuric amidochloride |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 428717853 | ImageFile=Mercuric-amidochloride-from-xtal-2000-3D-CM-ellipsoids.png | ImageSize=250px | IUPACName=mercuric azanide chloride | OtherNames=mercuric amidochloride mercury(II) amide chloride mercury(II) amidochloride ammoniated mercury |Section1={{Chembox Identifiers | InChI = 1/ClH.Hg.H2N/h1H;;1H2/q;+2;-1/p-1/rClH2HgN/c1-2-3/h3H2 | InChIKey = WRWRKDRWMURIBI-CUFRCDTJAQ | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/ClH.Hg.H2N/h1H;;1H2/q;+2;-1/p-1 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = WRWRKDRWMURIBI-UHFFFAOYSA-M | CASNo_Ref = {{cascite|correct|??}} | CASNo=10124-48-8 | PubChem=3032553 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID=21106343 | SMILES = Cl[Hg]N | UNII_Ref = {{fdacite|changed|FDA}} | UNII = JD546Z56F0 }} |Section2={{Chembox Properties | Formula=ClH2HgN | MolarMass=252.065 g/mol | Appearance= | Density=5.56 g/cm3 | MeltingPt= | BoilingPt= | Solubility= |Section6={{Chembox Pharmacology | ATCCode_prefix = D08 | ATCCode_suffix = AK01 }} |Section7={{Chembox Hazards | MainHazards= | FlashPt= | AutoignitionPt = }}Mercuric amidochloride is an inorganic compound with the formula HgNH2Cl. It consists of a zig-zag 1-dimensional polymer (HgNH2)n with chloride counterions.[1][2] It arises from the reaction of ammonia and mercuric chloride. Addition of base converts it into "Millon's base," which has the formula [Hg2N]OH(H2O)x. A variety of related amido and nitrido materials with chloride, bromide, and hydroxide are known.[3] Before the toxicity of mercury was appreciated, mercuric amidochloride, known as "ammoniated mercury", was used as a topical antiseptic and disinfectant.[4][5] See also
References1. ^{{cite book |last=Wells |first=A.F. |year=1984 |title=Structural Inorganic Chemistry |location=Oxford |publisher=Clarendon Press |isbn=0-19-855370-6}}{{page needed|date=December 2014}} {{Mercury compounds}}{{DEFAULTSORT:Mercuric Amidochloride}}2. ^{{cite journal |last1=Lipscomb |first1=W. N. |year=1951 |title=The structure of mercuric amidochloride, HgNH2Cl |journal=Acta Crystallographica |volume=4 |issue=3 |pages=266–8 |doi=10.1107/S0365110X51000866}} 3. ^{{cite book |last1=Holleman |first1=A. F. |last2=Wiberg |first2=E. |title=Inorganic Chemistry |publisher=Academic Press |location=San Diego |year=2001 |isbn=0-12-352651-5}}{{page needed|date=December 2014}} 4. ^{{cite journal |vauthors=Aberer W, Gerstner G, Pehamberger H |title=Ammoniated mercury ointment: outdated but still in use |journal=Contact Dermatitis |volume=23 |issue=3 |pages=168–71 |date=September 1990 |pmid=2149317 |doi=10.1111/j.1600-0536.1990.tb04778.x}} 5. ^http://www.huidziekten.nl/allergie/stoffen/mercury-ammonium-chloride.htm{{full citation needed|date=December 2014}} 3 : Mercury compounds|Chlorides|Metal amides |
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