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词条 Myclobutanil
释义

  1. Stereoisomerism

  2. References

  3. External links

{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| ImageFile = Myclobutanil Grundstruktur V1.svg
| ImageSize = 150px
| ImageFile_Ref = {{chemboximage|correct|??}}
| ImageName = Kekulé, skeletal formula of myclobutanil
| IUPACName = 2-(4-Chlorophenyl)-2-(1,2,4-triazol-1-ylmethyl)hexanenitrile
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo = 88671-89-0
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 6336
| PubChem1 = 11077077
| PubChem1_Comment = (2R)
| PubChem2 = 38989055
| PubChem2_Comment = (2S)
| ChemSpiderID = 6096
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID1 = 9252226
| ChemSpiderID1_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID1_Comment = (2R)
| EINECS = 410-400-0
| UNNumber = 3077
| KEGG = C18477
| KEGG_Ref = {{keggcite|correct|kegg}}
| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 75281
| MeSHName = Systhane
| RTECS = XZ5257000
| Beilstein = 7138849
| SMILES = CCCCC(Cn1cncn1)(C#N)c1ccc(Cl)cc1
| StdInChI = 1S/C15H17ClN4/c1-2-3-8-15(9-17,10-20-12-18-11-19-20)13-4-6-14(16)7-5-13/h4-7,11-12H,2-3,8,10H2,1H3
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = HZJKXKUJVSEEFU-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
}}
|Section2={{Chembox Properties
| C=15 | H=17 | N=4 | Cl=1
| Appearance = Pale, yellow, translucent crystals
| MeltingPtC = 63 to 68
| BoilingPtC = 202 to 208
| BoilingPt_notes = at 130 Pa
| Solubility = 142{{nbsp}}mg⋅dm−3
}}
|Section3={{Chembox Hazards
| GHSPictograms = {{GHS exclamation mark}} {{GHS health hazard}} {{GHS environment}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|302|319|361|411}}
| PPhrases = {{P-phrases|273|281|305+351+338}}
| NFPA-H = 2
| NFPA-F = 1
| NFPA-R = 0
| FlashPt = >
| FlashPtC = 100
}}
| verifiedrevid = 462256248
}}Myclobutanil is a triazole chemical used as a fungicide. It is a steroid demethylation inhibitor, specifically inhibiting ergosterol biosynthesis.[1] Ergosterol is a critical component of fungal cell membranes. When heated, myclobutanil decomposes to produce corrosive and/or toxic fumes, including carbon monoxide, carbon dioxide, hydrogen chloride, hydrogen cyanide, and nitrogen oxides.[2][3] Myclobutanil is banned in Canada, Colorado, Washington, and Oregon for the production of medical and recreational marijuana; however, despite the Canadian ban, myclobutanil has been discovered in medical marijuana produced by at least one government licensed grower.[4] In Michigan, the current state action limit for myclobutanil is 200 ppb in cannabis products. [5]

Stereoisomerism

Myclobutanil (2 stereoisomers)
{{small>(S)-configuration}}{{small>(R)-configuration}}

References

1. ^{{cite web | url = http://www.kingtaichem.com/pro_f_MYCLOBUTANIL.htm | publisher = Kingtai Chemicals Co. | title = Myclobutanil Product Sheet}}
2. ^{{cite web|url=https://cameochemicals.noaa.gov/chemical/30020|title=MYCLOBUTANIL - CAMEO Chemicals - NOAA|first=NOAA Office of Response and Restoration, US|last=GOV|website=cameochemicals.noaa.gov}}
3. ^{{cite web | url = http://www.dow.com/webapps/include/GetDoc.aspx?filepath=productsafety/pdfs/noreg/233-01023.pdf&pdf=true | title = Product Safety Assessment: Myclobutanil}}
4. ^{{cite web|url=https://www.theglobeandmail.com/news/national/canadians-not-told-about-banned-pesticide-found-in-medical-marijuana-supply/article33443887/|title=Canadians not told about banned pesticide found in medical pot supply|publisher=|via=The Globe and Mail}}
5. ^{{cite web|url=https://www.michigan.gov/documents/lara/Department_Banned_Pesticide_Active_Ingredient_List_620039_7.pdf&pdf=true | title = Technical Bulletin}}

External links

  • {{PPDB|478}}
  • International Programme on Chemical Safety

2 : Fungicides|Triazoles

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