请输入您要查询的百科知识:

 

词条 Olympiadane
释义

  1. See also

  2. References

{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 445630363
| ImageFile = Olympiadane.svg
| ImageSize = 400px
| ImageAlt = Skeletal formula of olympiadane
| ImageFile1 = Olympiadane ions spacefill.png
| ImageSize1 = 400
| ImageAlt1 = Ball-and-stick models of the component ions of olympiadane
| IUPACName =
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo = 158394-29-7
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem =
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 26000999
| SMILES =c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F }}
|Section2={{Chembox Properties
| C=228 | H=236 | F=72 | N=12 | O=30 | P=12
| Appearance =
| Density =
| MeltingPt =
| BoilingPt =
| Solubility = }}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
}}

Olympiadane is a mechanically-interlocked molecule composed of five interlocking macrocycles that resembles the Olympic rings. The molecule is a linear pentacatenane or a [5]catenane. It was synthesized and named by Fraser Stoddart and coworkers in 1994.[1] The molecule was designed without any practical use in mind,[2] although other catenanes may have possible application to the construction of a molecular computer.

See also

  • Olympicene

References

1. ^{{ cite journal | first1 = D. B. | last1 = Amabilino | first2 = P. R. | last2 = Ashton | first3 = A. S. | last3 = Reder | first4 = N. | last4 = Spencer | first5= J. F. | last5 = Stoddart | title = Olympiadane | journal = Angew. Chem. Int. Ed. Engl. | volume = 33 | issue = 12 | pages = 1286–1290 | year = 1994 | doi = 10.1002/anie.199412861 }}
2. ^{{cite news|url = https://www.nytimes.com/1994/08/30/science/chemists-make-rings-of-interlocked-atoms-a-clue-to-life-s-origin.html|title = Chemists Make Rings Of Interlocked Atoms, A Clue to Life's Origin|first = M. W.|last = Browne|date = 30 August 1994|accessdate = 3 January 2016|newspaper = The New York Times}}
{{heterocyclic-stub}}

3 : Molecular topology|Hexafluorophosphates|Supramolecular chemistry

随便看

 

开放百科全书收录14589846条英语、德语、日语等多语种百科知识,基本涵盖了大多数领域的百科知识,是一部内容自由、开放的电子版国际百科全书。

 

Copyright © 2023 OENC.NET All Rights Reserved
京ICP备2021023879号 更新时间:2024/11/11 10:24:04