词条 | Olympiadane |
释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 445630363 | ImageFile = Olympiadane.svg | ImageSize = 400px | ImageAlt = Skeletal formula of olympiadane | ImageFile1 = Olympiadane ions spacefill.png | ImageSize1 = 400 | ImageAlt1 = Ball-and-stick models of the component ions of olympiadane | IUPACName = | OtherNames = |Section1={{Chembox Identifiers | CASNo = 158394-29-7 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = | ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} | ChemSpiderID = 26000999 | SMILES =c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F }} |Section2={{Chembox Properties | C=228 | H=236 | F=72 | N=12 | O=30 | P=12 | Appearance = | Density = | MeltingPt = | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }} Olympiadane is a mechanically-interlocked molecule composed of five interlocking macrocycles that resembles the Olympic rings. The molecule is a linear pentacatenane or a [5]catenane. It was synthesized and named by Fraser Stoddart and coworkers in 1994.[1] The molecule was designed without any practical use in mind,[2] although other catenanes may have possible application to the construction of a molecular computer. See also
References1. ^{{ cite journal | first1 = D. B. | last1 = Amabilino | first2 = P. R. | last2 = Ashton | first3 = A. S. | last3 = Reder | first4 = N. | last4 = Spencer | first5= J. F. | last5 = Stoddart | title = Olympiadane | journal = Angew. Chem. Int. Ed. Engl. | volume = 33 | issue = 12 | pages = 1286–1290 | year = 1994 | doi = 10.1002/anie.199412861 }} {{heterocyclic-stub}}2. ^{{cite news|url = https://www.nytimes.com/1994/08/30/science/chemists-make-rings-of-interlocked-atoms-a-clue-to-life-s-origin.html|title = Chemists Make Rings Of Interlocked Atoms, A Clue to Life's Origin|first = M. W.|last = Browne|date = 30 August 1994|accessdate = 3 January 2016|newspaper = The New York Times}} 3 : Molecular topology|Hexafluorophosphates|Supramolecular chemistry |
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