| 词条 | Retene |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 434992161 | ImageFile = Retene.png | ImageSize = | ImageName = Skeletal formula | ImageFile1 = Retene-3D-balls.png | ImageSize1 = 210px | ImageName1 = Ball-and-stick model | IUPACName = 7-Isopropyl-1-methylphenanthrene | OtherNames = Retene |Section1={{Chembox Identifiers | CASNo_Ref = {{cascite|correct|??}} | CASNo =483-65-8 | PubChem =10222 | EINECS = 207-597-9 | ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}} | ChemSpiderID = 9805 | InChI = 1/C18H18/c1-12(2)14-7-10-17-15(11-14)8-9-16-13(3)5-4-6-18(16)17/h4-12H,1-3H3 | InChIKey = NXLOLUFNDSBYTP-UHFFFAOYAL | StdInChI_Ref = {{stdinchicite|changed|chemspider}} | StdInChI = 1S/C18H18/c1-12(2)14-7-10-17-15(11-14)8-9-16-13(3)5-4-6-18(16)17/h4-12H,1-3H3 | StdInChIKey_Ref = {{stdinchicite|changed|chemspider}} | StdInChIKey = NXLOLUFNDSBYTP-UHFFFAOYSA-N | SMILES =Cc1cccc3c1ccc2cc(C(C)C)ccc23 |Section2={{Chembox Properties | Formula =C18H18 | MolarMass =234.33552 | Appearance = | Density = | MeltingPtC = 98.5 | BoilingPtC = 390 | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} Retene, methyl isopropyl phenanthrene or 1-methyl-7-isopropyl phenanthrene, C18H18, is a polycyclic aromatic hydrocarbon present in the coal tar fraction, boiling above 360 °C. It occurs naturally in the tars obtained by the distillation of resinous woods. It crystallizes in large plates, which melt at 98.5 °C and boil at 390 °C. It is readily soluble in warm ether and in hot glacial acetic acid. Sodium and boiling amyl alcohol reduce it to a tetrahydroretene, but if it heated with phosphorus and hydriodic acid to 260 °C, a dodecahydride is formed. Chromic acid oxidizes it to retene quinone, phthalic acid and acetic acid. It forms a picrate that melts at 123-124 °C. Retene is derived by degradation of specific diterpenoids biologically produced by conifer trees. The presence of traces of retene in the air is an indicator of forest fires; it is a major product of pyrolysis of conifer trees.[1]{{Failed verification|date=September 2016|talk=Unsupported that a major part of conifer pyrolysis}} It is also present in effluents from wood pulp and paper mills.[2] Retene, together with cadalene, simonellite and ip-iHMN, is a biomarker of higher plants, which makes it useful for paleobotanic analysis of rock sediments. The ratio of retene/cadalene in sediments can reveal the ratio of the genus Pinaceae in the biosphere.[3] Health EffectsA recent study has shown retene, which is a component of the Amazonian organic PM10, is cytotoxic to human lung cells. [4] References1. ^{{cite web|last1=Simonich|first1=Staci|title=Community Outreach and Education Program Presents Unsolved Mysteries of Human Health: How Scientists Study Toxic Chemicals|url=http://www.unsolvedmysteries.oregonstate.edu/GCMS_04.shtml|publisher=Oregon State University|archiveurl=https://web.archive.org/web/20080316183140/http://www.unsolvedmysteries.oregonstate.edu/GCMS_04.shtml|archivedate=16 Mar 2008|dead-url=yes|language=English|quote=The presence of the chemical retene (REE-teen) in the air is a good indication of burning vegetation.}} {{1911|wstitle=Retene|volume=23|page=202}}2. ^{{cite journal|journal=Chemosphere|volume=37|pages=219–235|year=1998|title=IDENTIFICATION OF LIPOPHILIC POLLUTANTS DISCHARGED FROM A FINNISH PULP AND PAPER MILL|author=J. Koistinen, M. Lehtonena, K. Tukia, M. Soimasuo, M. Lahtiperab and A. Oikari|pmid=9650265 | doi=10.1016/S0045-6535(98)00041-1|issue=2}} 3. ^{{cite journal|journal=Geophysical Research Abstracts|volume=7|pages=10201|year=2005|title=Vascular plant biomarkers as ancient vegetation proxies and their stratigraphic use for tracing paleoclimatic changes during Jurassic in Western Europe|author=Y. Hautevelle, R. Michels, F. Malartre and A. Trouiller|url=http://www.cosis.net/abstracts/EGU05/10201/EGU05-J-10201.pdf|format=abstract}} 4. ^{{Cite journal|last=Nilmara de Oliveira Alves, Alexandre Teixeira Vessoni, Annabel Quinet, Rodrigo Soares Fortunato, Gustavo Satoru Kajitani, Milena Simões Peixoto, Sandra de Souza Hacon, Paulo Artaxo, Paulo Saldiva, Carlos Frederico Martins Menck, Silvia Regina Batistuzzo de Medeiros|first=|date=September 7, 2017|title=Biomass burning in the Amazon region causes DNA damage and cell death in human lung cells.|journal=Scientific Reports|volume=7|pages=|via=|doi=10.1038/s41598-017-11024-3}} 2 : Petroleum products|Phenanthrenes |
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