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词条 Rubidium bromide
释义

  1. References

{{chembox
| verifiedrevid = 447546883
| ImageFile = Rubidium-bromide-3D-ionic.png
| ImageName = Rubidium bromide
| IUPACName = Rubidium bromide
| OtherNames = Rubidium(I) bromide
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 74217
| InChI = 1/BrH.Rb/h1H;/q;+1/p-1
| InChIKey = JAAGVIUFBAHDMA-REWHXWOFAB
| SMILES = [Rb+].[Br-]
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/BrH.Rb/h1H;/q;+1/p-1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = JAAGVIUFBAHDMA-UHFFFAOYSA-M
| CASNo = 7789-39-1
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 4670918
|Section2={{Chembox Properties
| Formula = RbBr
| MolarMass = 165.372 g/mol
| Appearance = white crystalline solid
| Density = 3.350 g/cm3
| MeltingPtC = 693
| BoilingPtC = 1340
| Solubility = 98 g/100 mL
| MagSus = −56.4·10−6 cm3/mol
|Section3={{Chembox Hazards
| ExternalSDS =
| RPhrases =
| SPhrases =
| FlashPt = Non-flammable
|Section8={{Chembox Related
| OtherAnions = Rubidium fluoride
Rubidium chloride
Rubidium iodide
Rubidium astatide
| OtherCations = Lithium bromide
Sodium bromide
Potassium bromide
Caesium bromide
Francium bromide
}}Rubidium bromide is the bromide of rubidium. It has a NaCl crystal structure, with a lattice constant of 685 picometres.[1]

There are several methods for synthesising rubidium bromide. One involves reacting rubidium hydroxide with hydrobromic acid:

RbOH + HBr → RbBr + H2O

Another method is to neutralize rubidium carbonate with hydrobromic acid:

Rb2CO3 + 2HBr → 2RbBr + H2O + CO2

Rubidium metal would react directly with bromine to form RbBr, but this is not a sensible production method, since rubidium metal is substantially more expensive than the carbonate or hydroxide; moreover, the reaction would be explosive.

References

1. ^{{cite journal|journal= Phys. Rev. B|volume=39|issue=17|pages=12838–12844 |year=1989|author1=G. Chern |author2=J. G. Skofronick |author3=W. P. Brug |author4=S. A. Safron |doi=10.1103/PhysRevB.39.12838|title=Surface phonon modes of the RbBr(001) crystal surface by inelastic He-atom scattering}}
  • WebElements. URL accessed March 1, 2006.
{{Rubidium compounds}}{{bromine compounds}}{{inorganic-compound-stub}}

4 : Rubidium compounds|Bromides|Metal halides|Alkali metal bromides

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