词条 | Rubidium bromide |
释义 |
| verifiedrevid = 447546883 | ImageFile = Rubidium-bromide-3D-ionic.png | ImageName = Rubidium bromide | IUPACName = Rubidium bromide | OtherNames = Rubidium(I) bromide |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 74217 | InChI = 1/BrH.Rb/h1H;/q;+1/p-1 | InChIKey = JAAGVIUFBAHDMA-REWHXWOFAB | SMILES = [Rb+].[Br-] | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/BrH.Rb/h1H;/q;+1/p-1 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = JAAGVIUFBAHDMA-UHFFFAOYSA-M | CASNo = 7789-39-1 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 4670918 |Section2={{Chembox Properties | Formula = RbBr | MolarMass = 165.372 g/mol | Appearance = white crystalline solid | Density = 3.350 g/cm3 | MeltingPtC = 693 | BoilingPtC = 1340 | Solubility = 98 g/100 mL | MagSus = −56.4·10−6 cm3/mol |Section3={{Chembox Hazards | ExternalSDS = | RPhrases = | SPhrases = | FlashPt = Non-flammable |Section8={{Chembox Related | OtherAnions = Rubidium fluoride Rubidium chloride Rubidium iodide Rubidium astatide | OtherCations = Lithium bromide Sodium bromide Potassium bromide Caesium bromide Francium bromide }}Rubidium bromide is the bromide of rubidium. It has a NaCl crystal structure, with a lattice constant of 685 picometres.[1] There are several methods for synthesising rubidium bromide. One involves reacting rubidium hydroxide with hydrobromic acid: RbOH + HBr → RbBr + H2O Another method is to neutralize rubidium carbonate with hydrobromic acid: Rb2CO3 + 2HBr → 2RbBr + H2O + CO2 Rubidium metal would react directly with bromine to form RbBr, but this is not a sensible production method, since rubidium metal is substantially more expensive than the carbonate or hydroxide; moreover, the reaction would be explosive. References1. ^{{cite journal|journal= Phys. Rev. B|volume=39|issue=17|pages=12838–12844 |year=1989|author1=G. Chern |author2=J. G. Skofronick |author3=W. P. Brug |author4=S. A. Safron |doi=10.1103/PhysRevB.39.12838|title=Surface phonon modes of the RbBr(001) crystal surface by inelastic He-atom scattering}}
4 : Rubidium compounds|Bromides|Metal halides|Alkali metal bromides |
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