请输入您要查询的百科知识:

 

词条 Seamanite
释义

  1. History

  2. Description

  3. Distribution

  4. Crystallography

  5. Notes

  6. References

     Bibliography 

  7. Further reading

  8. External links

{{Infobox mineral
| name = Seamanite
| category = Borate minerals
| boxwidth = 280px
| boxbgcolor =
| image = Seamanite-zr17a.jpg
| imagesize = 260px
| caption = Seamanite crystals on a rock sample
(5 x 4 x 3 cm)
| formula = Mn3[B(OH)4](PO4)(OH)2[1]
| molweight = 372.64 g/mol[1]
| strunz = 6.AC.65[1]
| dana = 43.4.5.1[1]
| system = Orthorhombic
| class = Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)[5]
| symmetry = Pbnm
| unit cell = a = 7.811 Å, b = 15.114 Å
c = 6.691 Å, Z = 4
| color = yellow, yellow-brown, pink[2]
| habit = acicular[1]
| twinning =
| cleavage = distinct on {001}[5]
| fracture = brittle[1]
| tenacity = brittle[5]
| mohs = 4[2]
| luster = vitreous[1]
| polish =
| refractive = nα = 1.640,
nβ = 1.663,
nγ = 1.665[13]
| opticalprop =
| birefringence = δ = 0.025[2]
| 2V = ≈40°[3]
| dispersion = weak[2]
| pleochroism =
| fluorescence= none[1]
| absorption =
| streak = white[1]
| gravity =
| density = 3.08–3.128 g/cm3[5]
| melt =
| fusibility =
| diagnostic =
| solubility = in cold, dilute acids[2]
| diaphaneity = transparent[5]
| other =
| references = [4]
}}

Seamanite, named for discoverer Arthur E. Seaman, is a rare manganese boron phosphate mineral with formula Mn3[B(OH)4](PO4)(OH)2. The yellow to pink mineral occurs as small, needle-shaped crystals. It was first discovered in 1917 from a mine in Iron County, Michigan, United States and identified in 1930. {{As of|2012}}, seamanite is known from four sites in Michigan and South Australia.

History

In 1917, Arthur E. Seaman collected a mineral sample from the Chicagon Mine in Iron County, Michigan.{{#tag:ref|Some sources list it as the Chicagoan Mine[1]|group=lower-alpha|name=mine_name}} He correctly believed it to be a new mineral species based on a qualitative analysis of its composition by F. B. Wilson. World War I delayed further study of the mineral until 1929. A study in 1930 proved it to be a new mineral and named it seamanite in honor of Seaman. They cited his career as a professor of geology and mineralogy and his contributions to the field as reasons for the naming.[5]

The original analysis of the mineral in 1930 suggested seamanite to be a hydrated salt.[6] However, in 1971, the mineral was determined to be the coordination compound Mn3[B(OH)4](PO4)(OH)2.[7]

Description

Seamanite is a transparent, yellow to pink mineral that occurs as needle-shaped crystals.[1] Seamanite is a brittle mineral with a mohs hardness of 4.[2] It is found in the crevices of fractured siliceous rock.[5] The type occurrence was found in association with small crystals of calcite, thin coatings of manganese oxide,[5] and fibrous sussexite.[8] Seamanite has also been found with shigaite.[9]

Distribution

{{As of|2012}}, seamanite is known from four locations: the Cambria-Jackson Mine in Marquette County, Michigan, the Chicagon Mine and the Bengal Mine in Iron County, Michigan, and the Iron Monarch open cut in the Eyre Peninsula, South Australia.[2]

The type material is stored at Michigan Technological University in Houghton, Michigan, and at the National Museum of Natural History in Washington, D.C. as sample 96282.[4]

Crystallography

Seamanite is formed of acicular crystals elongated along [001] and showing the faces {110} and {111} up to one centimeter. It has an orthorhombic crystal system and the Pbnm space group. The parameters of its unit cell are: a=7.811 Å, b=15.114 Å, c=6.691 Å, Z=4 units per unit cell.[4]

Notes

1. ^{{cite web|title=Seamanite Mineral Data|url=http://www.webmineral.com/data/Seamanite.shtml |publisher=Webmineral |accessdate=April 13, 2012}}
2. ^{{cite web|title=Seamanite|url=http://www.mindat.org/min-3599.html|publisher=Mindat|accessdate=April 13, 2012}}
3. ^Kraus, p. 222
4. ^{{cite web|title=Seamanite|url=http://www.handbookofmineralogy.org/pdfs/seamanite.pdf|work=Handbook of Mineralogy|publisher=Mineral Data Publishing|accessdate=April 13, 2012|format=PDF}}
5. ^Kraus, p. 220.
6. ^Kraus, p. 223–5
7. ^Moore, p. 1527.
8. ^Slawson, p. 575
9. ^{{cite web|title=Seamanite - Photo Gallery|url=http://www.mindat.org/gallery.php?cform_is_valid=1&min=3599&cf_pager_page=1|publisher=Mindat|accessdate=April 13, 2012}}

References

{{Reflist}}

Bibliography

  • {{cite journal|last1=Kraus|first1=E.H.|last2=Seaman|first2=W.A.|last3=Slawson|first3=C.B.|title=Seamanite, a new manganese phospho-borate from Iron County, Michigan|journal=American Mineralogist|date=June 1930|volume=15|issue=6|pages=220–225|publisher=Mineralogical Society of America|url=http://www.minsocam.org/ammin/AM15/AM15_220.pdf|accessdate=April 13, 2012|format=PDF}}
  • {{cite journal|last1=Moore|first1=Paul B.|last2=Ghose|first2=Subrata|title=A Novel Face-Sharing Octahedral Trimer in the Crystal Structure of Seamanite|journal=American Mineralogist|publisher=Mineralogical Society of America|date=September–October 1971|volume=56|issue=9 & 10|pages=1527–1538|url=http://www.minsocam.org/ammin/am56/am56_1527.pdf|accessdate=April 13, 2012|format=PDF}}
  • {{cite journal|last=Slawson|first=Chester B.|title=Sussexite from Iron County, Michigan|journal=American Mineralogist|publisher=Mineralogical Society of America|date=December 1934|volume=19|issue=12|pages=575–578|url=http://www.minsocam.org/ammin/AM19/AM19_575.pdf|accessdate=April 13, 2012|format=PDF}}

Further reading

  • {{cite journal|last1=Huminicki|first1=Danielle M.C.|last2=Hawthorne|first2=Frank C.|title=Hydrogen Bonding in the Crystal Structure of Seamanite|journal=The Canadian Mineralogist|year=2002|volume=40|issue=|pages=923–928|url=http://rruff.geo.arizona.edu/doclib/cm/vol40/CM40_923.pdf|accessdate=April 14, 2012|format=PDF|doi=10.2113/gscanmin.40.3.923}}
  • {{cite journal|last1=McConnell|first1=Duncan|last2=Pondrom|first2=Walter L., Jr.|title=X-ray Crystallography of Seamanite|journal=American Mineralogist|publisher=Mineralogical Society of America|date=July 1941|volume=26|issue=7|pages=446–447|url=http://www.minsocam.org/ammin/AM26/AM26_446.pdf|accessdate=April 13, 2012|format=PDF}}

External links

{{commonscat-inline|Seamanite}}

4 : Borate minerals|Phosphate minerals|Manganese minerals|Orthorhombic minerals

随便看

 

开放百科全书收录14589846条英语、德语、日语等多语种百科知识,基本涵盖了大多数领域的百科知识,是一部内容自由、开放的电子版国际百科全书。

 

Copyright © 2023 OENC.NET All Rights Reserved
京ICP备2021023879号 更新时间:2024/11/13 1:44:53